The article considers the possibility of reducing the man-made load on surface and ground waters in Lysychansk-Severodonetsk industrial agglomeration caused by numerous sludge collectors and tailings storage facilities of various industries formed many decades ago. The paper provides information on the location and technical condition of the sludge collectors of the liquidated "LYSSODA" manufacture (Luhansk oblast), the amount of waste currently stored in them as well as the impact of these wastes on the quality of groundwater in the area where the sludge collectors are located. The work shows one of several possible options for using such wastes as a valuable secondary mineral raw material for obtaining a marketable product. The averaged data on the chemical composition of the solid phase of sludge and indicators of the liquid phase composition are given. According to the results of the analysis of scientific and technical information, it has been found that such wastes can ultimately be used for the production of anti-icing reagents. The obtained results of research on the dependence of the freezing point of working solutions on the concentration of salts, including the added corrosion inhibitors (triethanolamine, hexamethylenetetramine), indicate the feasibility of using soda ash production waste to obtain effective liquid anti-icing reagents without a mechanical component, while the optimal amount of added corrosion inhibitors is 0.5% wt. Such reagents can be used both undiluted at temperatures up to minus 20oC and strengthened to 15-20% wt. by calcium chloride at temperatures up to minus 40°C with consumption on highways at the level of about 100 g/m2 of the treated surface.
1. Borodina, N. A., & Vyrozhemskyi, V. K. (2004). Ocinka vplyvu khlorystykh protyozhelednykh materialiv na navkolyshnje seredovyshhe pry zymovomu utrymanni avtomobiljnykh dorigh. Roads and bridges: сollection of scientific papers, 2, 14-17.
2. Kostrzhyckyi, A. I., Kalinkov, O. Ju., Tishhenko, V. M., & Berehova, O. M. (2008). Fizychna ta kolojidna khimija: Navchalnyi posibnyk. Kyiv: Сentr uchbovoji literatury. Retrieved from http://194.44.152.155/elib/local/r158.pdf
3. LLC "Luhansk Geoecocenter". (2007). Informatsiya o sostoyanii kachestva podzemnykh vod na ploshchadi vliyaniya nakopiteley OAO «Lisichanskaya soda» v ІІ kvartale 2007 g. Luhansk: Fondy OAO «Lisichanskaja soda».
4. Lure, Yu. (2012). Analiticheskaya khimiya promyshlennykh stochnykh vod. Moscow: Knyga po zaprosu. Retrieved from http://booksshare.net/books/chem/lure-uu/1984/files/analhimpromstokvod19...
5. Mokhonko, V. I. (2015). Otsenka vliyaniya tekhnogennykh faktorov na aktivizatsiyu melo-mergelnogo karstogeneza. First independent scientific journal, 1, 52-57. Retrieved from https://cyberleninka.ru/article/n/otsenka-vliyaniya-tehnogennyh-faktorov...
6. Mokhonko, V. І., Zubtsov, Ye. I., Ozheredova, M. A., & Suvorin, O. V. (2020). Vplyv shlamonakopychuvachiv sodovogho vyrobnyctva na stan navkolyshnjogho seredovyshha. Suchasni tekhnologhiji v nauci ta osviti: materialy III Mizhnarodnoji naukovo-praktychnoji konferenciji, 27-28 ljutogho 2020, Severodonetsk, 122-124. Retrieved from http://filelibsnu.at.ua/conference/2019-2020/suchasni_tehnologii_2-DOI-2-.pdf
7. Morozov, I. V., Achkeeva, M. V., & Kolmychkov, N. S. (2001). RU Patent No 2167179. Retrieved from https://patents.google.com/patent/RU2167179C1/ru?oq=2167179
8. Mikhaylova, Ye. A., Loboyko, A. Ya., Bagrova, I. V., & Panasenko, V. A. (2010). Proizvodstvennye otkhody sodovykh predpriyatiy i vozmozhnye puti ikh utilizatsii. Bulletin of the National Technical University “Kharkiv Polytechnic Institute”, 11, 79-84. Retrieved from http://repository.kpi.kharkov.ua/handle/KhPI-Press/19193
9. Nikolaieva, I., Lenko, G., Avіerin, D., & Lobodzynskyi, O. (2020). Doslidzhennja potochnogho stanu khvostoskhovyshh Donbasu shhodo jikhnjogho mozhlyvogho avarijnogho vplyvu na vodni ob'jekty. Kyiv: Orghanizacija z bezpeky ta spivrobitnyctva v Jevropi ta Derzhavne aghenstvo vodnykh resursiv Ukrajiny. Retrieved from https://www.osce.org/files/f/documents/9/9/486259.pdf
10. Optimum system. Goods for laboratories and production. (2020). Pryncyp diji i asortyment protyozhelednykh reaghentiv. Retrieved from https://www.systopt.com.ua/article-pryncyp-diyi-i-asortyment-protyozhele...
11. Orlova, V. T., Danilov, V. P., Bykov, A. V., Tingaev, O. P., & Nikolaev, V. V. (2001). RU Patent No 2173329. Retrieved from https://patents.google.com/patent/RU2173329C2/ru?oq=2173329
12. Ravdel, А. А., & Ponomareva, A. М. (Ed.). (1983). Kratkiy spravochnik fiziko-khimicheskikh velichin. Leningrad: Khimiya. URL: https://ru.djvu.online/file/nD1tBF6uBn9N8
13. Sіedov, A. V. (2018). Analiz dosvidu vykorystannja kompleksnykh protyozhelednykh materialiv dlja borotjby iz zymovoju slyzjkistju na avtomobiljnykh doroghakh. Materialy Vseukrajinsjkoji naukovo-praktychnoji Internet-konferenciji «Budivnyctvo ta ekspluatacija ob'jektiv transportnoji infrastruktury», Kharkiv, 113-118.
14. Sіedov, A. V., & Fomenko, O. A. (2019). Vplyv khlorystykh protyozhelednykh materialiv na bezpeku dorozhnjogho rukhu v zymovyj period. Bulletin of Kharkiv National Automobile and Highway University, 86(2), 131-134. doi: https://doi.org/10.30977/BUL.2219-5548.2019.86.2.130
https://doi.org/10.30977/BUL.2219-5548.2019.86.2.130
15. Simonova, S. (Ed.). (2004). Novyy spravochnik khimika i tekhnologa. T. 4: Khimicheskoe ravnovesie. Svoystva rastvorov. St. Petersburg: ANO NPO Professional. Retrieved from http://chemistry-chemists.com/chemister/Spravochniki/spravochniki.htm
16. State Scientific Research аnd Design Institute оf Basic Chemistry “NIOCHIM”. (2020). Novyj protyozhelednyj material. Retrieved from http://niochim.kharkov.ua/wp-content/uploads/2020/10/New-anti-icing-mate...
17. Stromberg, A. G, & Semchenko, D. P. (2009). Fizicheskaya khimiya. Moscow: Vysshaya shkola. Retrieved from https://library.tou.edu.kz/fulltext/buuk/b661.pdf
18. Suvorin, O. V, Ozheredova, M. A., Zubtsov, Ye. I., & Shorokhov, M. M. (2020). Vidkhody vyrobnyctva kaljcynovanoji sody jak perspektyvna vtorynna syrovyna. Tekhnologhija-2020: XXIII materialy mizhnarodnoji naukovo-tekhnichnoji konferenciji, 24-25 kvitnja 2020, Severodonetsk, 11-13. Retrieved from http://filelibsnu.at.ua/conference/Technology_2020.pdf
19. Tytarenko, A. O., Yarovyi, Ye. V., Ozheredova, M. A., & Zubtsov, Ye. I. (2020). Analiz metodiv utylizaciji shlamiv sodovogho vyrobnyctva. Tekhnologhija-2020: XXIII materialy mizhnarodnoji naukovo-tekhnichnoji konferenciji, 24-25 kvitnja 2020, Severodonetsk, 88-89. Retrieved from http://filelibsnu.at.ua/conference/Technology_2020.pdf
20. Derzhavne aghentstvo avtomobiljnykh dorigh Ukrajiny Ukravtodor. (2011). Zastosuvannja inghibitoru koroziji v khlorydnykh protyozhelednykh materialakh: TTR 218-00018112/31911658-408:2011. Retrieved from https://ukravtodor.gov.ua/
21. Zakrevskyі, A. I., Popelysh, I. I., Koritchuk, S. O., & Kolosivskyi, M. L. (2016). Aerodromni antyozheledni khimreaghenty. Automobile Roads аnd Road Construction, 96, 19-32. Retrieved from https://dspace.nau.edu.ua/handle/NAU/54533?mode=full
22. Zhandullaeva, M. S, Iskenderov, A. M., & Atakuziev, T. A. (2011). Ispolzovanie otkhodov sodovogo proizvodstva v tsementnoy promyshlennosti v kachestve mineralizatora. Production of building materials and products using industrial waste: Proceedings Scientific publication, 7, 252-257.
23. Zubtsov, Ye. I., Mokhonko, V. I., Ozheredova, M. A., & Suvorin, O. V. (2020). Suchasnyj stan ta shljakhy rozrobky tekhnoghennykh rodovyshh Sjevjerodonecjko-Lysychansjko-Rubizhansjkoji aghlomeraciji na prykladi nakopychuvachiv vidkhodiv sodovogho vyrobnyctva. Suchasni tekhnologhiji v nauci ta osviti: materialy III Mizhnarodnoji naukovo-praktychnoji konferenciji, 27-28 ljutogho 2020, Severodonetsk, 128-130. Retrieved from http://filelibsnu.at.ua/conference/2019-2020/suchasni_tehnologii_2-DOI-2...