Influence of metal-containing polymer-silicate filler on the technological properties of polypropylene

2020;
: 214-219
1
Lviv Polytechnic National University
2
Lviv Polytechnic National University
3
Lviv Polytechnic National University, The John Paul II Catholic University of Lublin
4
Lviv Polytechnic National University
5
Lviv Polytechnic National University

The influence of Ni-containing polymer-silicate filler on the technological properties of polypropylene is presented. It was found that the introduction of silicate fillers modified by polyvinyl alcohol change the flow patterns of polypropylene melts, in particular viscosity increases and anomalous viscosity shifts. The change of thermomechanical curves of polypropylene under the action of modified silicate fillers is shown. It is noted that composite materials based on polypropylene and modified silicate filler are characterized by reduced melt flow index, reduced values of technological shrinkage and slightly increased water absorption.

1.   Bykov E. A., Dehtyarev V.V. (2006). Modern fillers Questions of chemistry and chemical engineering an important factor in improving the competitiveness of composites. Plastic masses, 1, 32-36.
2. Moumita Kotal, Anil K. Bhowmick (2015). Polymer nanocomposites from modified clays: Recent advances and challenges. Progress in Polymer Science. 51 (13), 1127-1187. https://doi.org/10.1016/j.progpolymsci.2015.10.001
https://doi.org/10.1016/j.progpolymsci.2015.10.001
3.   García M. (2004). Polymer - inorganic nanocomposites, influence of colloidal silica. Thesis university of Twente.
4. Yiu-Wing Mai, Zhong-Zhen Yu, (2006). Polymer Nanocomposites, Cambridge: Woodhead Publishing Limited.
5. Rakesh K. Gupta, Elliot Kennel, Kwang-Jea Kim (2009) Polymer Nanocomposites Handbook. Cambridge: CRC Press.
6. Mittal V. (2009) Polymer Nanocomposites: Advances in Filler Surface Modification Technique. - New York: Nova Science Publ.
7. Dibyendu Mondal, Md. Masud R. Mollick, Biplab Bhowmick, Dipanwita Maity, Mrinal K. Bain, Dipak Rana, Asis Mukhopadhyay, Kausik Dana, Dipankar Chattopadhyay (2013) Effect of poly(vinylpyrrolidone) on the morphology and physical properties of poly(vinyl alcohol)/sodium montmorillonite  nanocomposite films, Progress in Natural Science: Materials International, 23 (6), 579-587.
https://doi.org/10.1016/j.pnsc.2013.11.009
8. Kerber M.L., Vinogradov V.M., Golovkin G.S., Berlina A.A. (Eds.) (2008) Polimernyye kompozitsionnyye materialy // SP.: Professiya.
9.Voronin E. F., Nosach L.V., Pahlov E.M. (2007). Peculiarities of adsorption interactions on the surface of the aggregate nanosilica. Physical chemistry of nanomaterials and supramolecular structures, 1, 264-285.
10. Masyuk A. S., Levytskyi V. Ye. (2014). Regularities of obtaining of polymer-silicate composites from water-soluble silicates and polymers. Eastern-European Journal of Enterprise Technologies, 6/6(72), 29-33.
https://doi.org/10.15587/1729-4061.2014.30870
11. Levytskyi, V.Ye., Masyuk, A.S., Suberlyak, O.V. (2017) Preparation and properties of polymer-silicate composites based on hydrophilic polymers // Voprosy Khimii i Khimicheskoi Tekhnologii. 6, 68-74.
12. Bishop E. (1976). Indicators. Moskow «Myr».
13. Levytskyi V., Masyuk A., Katruk D. and Bratychak M. (2016)Regularities of obtaining, morphology and properties of metal-containing polymer-silicate materials and polyester composites on their basis Chemistry & Chemical technology. 1, 35-40.
https://doi.org/10.23939/chcht10.01.035