In the work presents to test of the possibility of using halogenated vegetable oil to obtain polymeric materials. The result of the conducted research the development of the methodology of halogenation of sunflower oil presented and confirmed of its structure by the method of IR spectroscopy. The obtained halogenated oil was used to reactions of interact with compounds of different functionality. Synthesized materials was using for obtain polymer composite materials by thermopolymerization with vinyl monomers.
1. Richard P. Pohanish. (2017) Sittig's Handbook of Toxic and Hazardous Chemicals and Carcinogens. Seven Edition, Volume 1: A-D. PP. 1224-1225.
https://doi.org/10.1016/B978-0-323-38968-6.00001-6
2. Hideshige Takada, Hrissi K. Karapanagioti. (2019) Hazardous Chemicals Associated with Plastics in the Marine Environment. PP. 9-11. doi: 10.1007/978-3-319-95568-1.
https://doi.org/10.1007/978-3-319-95568-1
3. P. Ventrice, D. Ventrice, E. Russo, and G. De Sarro (2013) Phthalates: European regulation, chemistry, pharmacokinetic and related toxicity. Environmental Toxicology and Pharmacology. Vol. 36, No.1, PP. 88-96, 2013.
https://doi.org/10.1016/j.etap.2013.03.014
4. Statista, Global production of vegetable oils from 2000/01 to 2018/19 (in million metric tons), accessed by June 14, 2019. <https://www.statista.com/statistics/263978/global-vegetable-oil-producti...
5. L. Maisonneuve, T. Lebarbé, E. Grau and H. Cramail. (2013). Structure-properties relationship of fatty acid-based thermoplastics as synthetic polymer mimics. Polym. Chem., 2013, 4, .5472 -5517.
https://doi.org/10.1039/c3py00791j
6. X. Meng, G. Chen and Y. Wang. (2008). Biodiesel production from waste cooking oil via alkali catalyst and its engine test. Fuel Process. Technol., 89, 851 -857.
https://doi.org/10.1016/j.fuproc.2008.02.006
7. S. M. Danov, O. A. Kazantsev, A. L. Esipovich, A. S. Belousov, A. E. Rogozhin and E. A. Kanakov (2017) Recent advances in the field of selective epoxidation of vegetable oils and their derivatives: a review and perspective. Catal. Sci. Technol., 7, 3659-3675. https://doi.org/10.1039/C7CY00988G
https://doi.org/10.1039/C7CY00988G
8. M. M. Gui, K. T. Lee and S. Bhatia. Feasibility of edible oil vs. Non-edible oil vs. Waste edible oil as biodiesel feedstock. 2008.
9. Jianming Chen, Marc de Liedekerke Beaufort, Lucas Gyurik, Joren Dorresteijn, Matthias Otte and Robertus J. M. Klein Gebbink. (2019) Highly efficient epoxidation of vegetable oils catalyzed by a manganese complex with hydrogen peroxide and acetic acid. Green Chem. 21. 2436-2447. https://doi.org/10.1039/C8GC03857K
https://doi.org/10.1039/C8GC03857K
10. Josiah McNutt, Quan (Sophia) He. (2016) Development of biolubricants from vegetable oils via chemical modification. Journal of Industrial and Engineering Chemistry. Volume 36, 25 April, 1-12.
https://doi.org/10.1016/j.jiec.2016.02.008
11. Samira Moqadam and Mehdi Salami-Kalajahi. (2015) Halogenated sunflower oil as a precursor for synthesis of polysulfide polymer. e-Polymers. Volume 16: Issue 1. 33-39. https://doi.org/10.1515/epoly-2015-0152.
https://doi.org/10.1515/epoly-2015-0152
12. Jumain Jalil, Mohd; Suhada Azmi, Intan; Rafizan Mohammad Daud, Ahmad. (2017). An Overview of Epoxidation of Vegetable Oils with Peracid- Reaction Mechanism. Recent Innovations in Chemical Engineering (Formerly Recent Patents on Chemical Engineering). Volume 10, Number 1. 4-11(8). https://doi.org/10.2174/2405520410666170614113317
https://doi.org/10.2174/2405520410666170614113317
13. S. M. Danov, O. A. Kazantsev, A. L. Esipovich, A. S. Belousov, A. E. Rogozhin and E. A. Kanakov. (2017) Recent advances in the field of selective epoxidation of vegetable oils and their derivatives: a review and perspective. Catal. Sci. Technol. Issue 17, 3659-3675.
https://doi.org/10.1039/C7CY00988G
14. Sébastien Leveneur. (2017) Thermal Safety Assessment through the Concept of Structure-Reactivity: Application to Vegetable Oil Valorization. Org. Process Res. Dev. 21, 4, 543-550. https://doi.org/10.1021/acs.oprd.6b00405.
https://doi.org/10.1021/acs.oprd.6b00405
15. Lastukhin Yu.O., Voronov S.A. (2009) Orhanichna khimiia. Lviv, Tsentr Yevropy. P.864.