Metal-complex macroinitiators were successfully applied for the synthesis of polymer nanocomposites with core-shell structure by two-stage water dispersed polymerization. On the first stage, formation of monodispersed polymer particles of desired size and functionality is achieved by target variation of macroinitiator concentration, content of metal cations in its structure, and pH of medium. Initiation of grafted polymerization from the surface of seeded particles is provided by residual peroxide moieties of macroinitiator.
[1] Sounderya N., Zhang Y.: Recent Pat. Biomed. Eng., 2008, 1, 34. https://doi.org/10.2174/1874764710801010034.
https://doi.org/10.2174/1874764710801010034
[2] Bawa P., Pillay V., Choonara Y., du Toit L.: Biomed. Mater., 2009, 4, 022001. https://doi.org/10.1088/1748-6041/4/2/022001.
https://doi.org/10.1088/1748-6041/4/2/022001
[3] Shunichi K., Niichiro H., Toshihide S. et al.: Pat. US 4173696, Publ. Nov. 06, 1979.
[4] Ivanchov S.: Peroxidsoderzhashchiye Iniciatory Emulsionnoy Polymerizacii Vinilnyh Monomerov [in:] Emanuel N. (Ed.) Khimiya Organicheskikh Peroxidov. VPI, Volgograd 1982, 115-136.
[5] Pavluchenko V., Lesnikova N., Ivanchov S. et al.: Vsesoyuzniy Seminar po Khimii Ozona, Tbilisi, 1981, 94.
[6] Ivanchev S., Pavluchenko V., Byrdina N.: J. Polym. Sci. A, 1987, 25, 47. https://doi.org/10.1002/pola.1987.080250106.
https://doi.org/10.1002/pola.1987.080250106
[7] Tauer K., Antonietti M., Rosengarten L., Muller H.: Macromol. Chem. Phys., 1998, 95, 897. https://doi.org/10.1002/(SICI)1521-3935(19980501)199:5<897::AID-MACP897>3.0.CO;2-X.
https://doi.org/10.1002/(SICI)1521-3935(19980501)199:5<897::AID-MACP897>3.0.CO;2-X
[8] Tauer K., Kosmella S.: Polym. Int., 1993, 30, 253. https://doi.org/10.1002/pi.4990300219.
https://doi.org/10.1002/pi.4990300219
[9] Dicke H.-R., Heitz W.: Colloid Polym. Sci., 1982, 260, 3. https://doi.org/10.1007/BF01447669.
https://doi.org/10.1007/BF01447669
[10] Martinek K., Yatsimirski A., Levashov A., Berezin I.: Kinetic Theory and Mechanism of Micellar Effects in Chemical Reactions [in:] Mittel K. (Ed.) Micellization, Solubilization, and Microemulsions, Springer, New York 1977, 489-508. https://doi.org/10.1007/978-1-4613-4157-4_1.
https://doi.org/10.1007/978-1-4613-4157-4_1
[11] Ivanchev S., Pavlyuchenko V., Rozhkova D.: Vysokomol. Soed. Ser. A, 1974, 16, 893.
[12] Messner B., Quis P., Schmitt G. et al.: Pat. US 5403883 A.; Publ. Apr. 04, 1995.
[13] Bhattacharya A., Misra B.: Prog. Polym. Sci., 2004, 29, 767. https://doi.org/10.1016/j.progpolymsci.2004.05.002.
https://doi.org/10.1016/j.progpolymsci.2004.05.002
[14] Guyot A., Tauer K.: Adv. Polym. Sci., 1994, 111, 43. https://doi.org/10.1007/BFb0024126.
https://doi.org/10.1007/BFb0024126
[15] Piirma I.: Polymeric Surfactants. Marcel Dekker Inc., New York–Basel 1992.
[16] Voronov S., Varvarenko S.: Peroksydovmisni Macromolekuly na Mezhi Rozdilu Phaz. Naukovi Publikaciyi Nacionalnoho Universitetu "Lvivska Polytechnika", Lviv 2011.
[17] Zaichenko A., Mitina N., Shevchuk O. et al.: Macromol. Symp., 2001, 164, 25. https://doi.org/10.1002/1521-3900(200102)164:1<25::AID-MASY25>3.0.CO;2-V.
https://doi.org/10.1002/1521-3900(200102)164:1<25::AID-MASY25>3.0.CO;2-V
[18] Voronov S., Kiselyov Eu., Minko S. et al.: J. Polym. Sci. A., 1996, 34, 2507. https://doi.org/10.1002/(SICI)1099-0518(19960915)34:12<2507::AID-POLA24>3.0.CO;2-B.
https://doi.org/10.1002/(SICI)1099-0518(19960915)34:12<2507::AID-POLA24>3.0.CO;2-B
[19] Tauer K.: Polymer Nanoparticles with Surface Active Initiators and Polymer Initiators [in:] V. Mittal (Ed.) Advanced Polymer Nanoparticles: Synthesis and Surface Modifications, CRC Press, Boca-Raton 2010, 329-359.
https://doi.org/10.1201/EBK1439814437-c11
[20] Solomko N., Dron I., Budishevskaya O., Voronov S.: Procedia Chem., 2009, 1, 1567. https://doi.org/10.1016/j.proche.2009.11.005
https://doi.org/10.1016/j.proche.2009.11.005
[21] Pich A., Richter S., Alder H.-J. et.al.: Macromol. Symp., 2001, 164, 11. https://doi.org/10.1002/1521-3900(200102)164:1<11::AID-MASY11>3.0.CO;2-K.
https://doi.org/10.1002/1521-3900(200102)164:1<11::AID-MASY11>3.0.CO;2-K
[22] Adler H.-J.P., Pich A., Henke A. et al.: New Core-Shell Dispersions with Reactive Groups [in:] E.Daniels (Ed.) ACS Symposium Series. Washington, DC; American Chemical Society, 2001, 276-292. https://doi.org/10.1021/bk-2002-0801.ch019.
https://doi.org/10.1021/bk-2002-0801.ch019
[23] Popadyuk A., Tarnavchyk I., Popadyuk N. et al.: React. Funct. Polym., 2013, 73, 1290. https://doi.org/10.1016/j.reactfunctpolym.2013.07.002.
https://doi.org/10.1016/j.reactfunctpolym.2013.07.002
[24] Budishevska O., Dronj I., Voronov A., et al.: React. Funct. Polym., 2009, 69, 785. https://doi.org/10.1016/j.reactfunctpolym.2009.06.006
https://doi.org/10.1016/j.reactfunctpolym.2009.06.006
[25] Cheng C., Shu J., Gong S. et al.: New J. Chem., 2010, 34, 163. https://doi.org/10.1039/B9NJ00307J.
https://doi.org/10.1039/B9NJ00307J
[26] Li G., Mohwald H., Shchukin D.: Chem. Soc. Rev., 2013, 42, 3628 https://doi.org/10.1039/C3CS35517A.
https://doi.org/10.1039/c3cs35517a
[27] Okubo M., Katsuta Y., Matsumoto T.: J. Polym. Sci. Polym. Lett., 1980, 18, 481. https://doi.org/10.1002/pol.1980.130180704
https://doi.org/10.1002/pol.1980.130180704
[28] Okubo M.: Macromol. Symp., 1990, 35-36, 307. https://doi.org/10.1002/masy.19900350119.
https://doi.org/10.1002/masy.19900350119
[29] Okubo M., Shiozaki M., Tsujihiro M., Tsukuda Y.: Colloid Polym. Sci., 1991, 269, 222. https://doi.org/10.1007/BF00665495.
https://doi.org/10.1007/BF00665495
[30] He X.-D., Ge X.-W., Wang M.-Z., Zhang Z.-C.: J. Appl. Polym. Sci., 2005, 98, 860. https://doi.org/10.1002/app.22181
https://doi.org/10.1002/app.22181
[31] Ramli R., Laftah W., Hashim S.: RSC Adv., 2013, 3, 15543. https://doi.org/10.1039/C3RA41296B.
https://doi.org/10.1039/c3ra41296b
[32] Jönsson J.-E., Karlsson O.J., Hassander H., Törnell B.: Eur. Polym. J.,2007, 43, 1322. https://doi.org/10.1016/j.eurpolymj.2007.01.027.
https://doi.org/10.1016/j.eurpolymj.2007.01.027
[33] Chern C.S.: Prog.Polym.Sci., 2006, 31, 443. https://doi.org/10.1016/j.progpolymsci.2006.02.001
https://doi.org/10.1016/j.progpolymsci.2006.02.001
[34] Shim S.-E., Cha Y.-J., Byun J.-M., Choe S.: J. Appl. Polym. Sci., 1999, 71, 2259. https://doi.org/10.1002/(SICI)1097-4628(19990328)71:13<2259::AID-APP17>3.0.CO;2-5.
https://doi.org/10.1002/(SICI)1097-4628(19990328)71:13<2259::AID-APP17>3.0.CO;2-5
[35] Gan D., Lyon L.: J. Am. Chem. Soc., 2001, 123, 7511. https://doi.org/10.1021/ja010609f.
https://doi.org/10.1021/ja010609f
[36] Li W.-H., Stöver H.D.H.: Macromolecules, 2000, 33, 4354. https://doi.org/10.1021/ma9920691.
https://doi.org/10.1021/ma9920691
[37] Chainey M., Hearn J., Wilkinson M.: Brit. Polym. J., 1981, 13, 132. https://doi.org/10.1002/pi.4980130310.
https://doi.org/10.1002/pi.4980130310
[38] Coen E., Lyons R., Gilbert R.: Macromolecules, 1996, 29, 5128. https://doi.org/10.1021/ma9600567.
https://doi.org/10.1021/ma9600567
[39] Huang Z., Wang C., Li Y., Wang Z.: Colloid Polym. Sci., 2012, 290, 979. https://doi.org/10.1007/s00396-012-2663-5.
https://doi.org/10.1007/s00396-012-2663-5
[40] Vanderhoff J., El Aasser M., Micale F. et al.: J. Disp. Sci. Tech., 1984, 5, 231. https://doi.org/10.1080/01932698408943220.
https://doi.org/10.1080/01932698408943220
[41] Vanderhoff J., Micale F., El Aasser M., Tseng C.M.: Pat. US 5106903, Publ. Apr. 21, 1992.
[42] Jeong Y.-S., Lee K-W., Ha H.-C.: Pat. US 20050176894, Publ. Aug. 11, 2005.
[43] Adelnia H., Gavgani J.N., Soheilmoghaddam M.: Colloid Polym. Sci., 2015, 293, 2445. https://doi.org/10.1007/s00396-015-3675-8.
https://doi.org/10.1007/s00396-015-3675-8
[44] Chu H., Wang H., Ni Z. et al.: Particuology, 2008, 6, 369. https://doi.org/10.1016/j.partic.2008.06.002.
https://doi.org/10.1016/j.partic.2008.06.002
[45] Liao X., Cheng J.; Li L. et al.: Polym. Polym. Compos., 2009, 17, 109.
[46] Huang B., Bai F., Yang X.-l., Huang W.-Q.: Chin. J. Polym. Sci., 2010, 28, 277. https://doi.org/10.1007/s10118-010-9089-7.
https://doi.org/10.1007/s10118-010-9089-7
[47] Okubo M., Nakagawa T.: Colloid Polym. Sci., 1992, 270, 853. https://doi.org/10.1007 / BF00657729.
[48] Okubo M., Shiozaki M.: Polym. Int., 1993, 30, 469. https://doi.org/10.1002/pi.4990300409.
https://doi.org/10.1002/pi.4990300409
[49] Minami H., Wang Z., Yamashita T., Okubo M.: Colloid Polym. Sci., 2003, 281, 246. https://doi.org/10.1007/s00396-002-0766-0.
https://doi.org/10.1007/s00396-002-0766-0
[50] Lu X., Xin Z.: Colloid Polym. Sci., 2006, 284, 1062. https://doi.org/10.1007/s00396-006-1482-y.
https://doi.org/10.1007/s00396-006-1482-y
[51] Sayer C., de Araujo P.H.: Synthesiz of Polymer Particles with Core-Shell Morphologies [in:] V. Mittal (Ed.) Advanced Polymer Nanoparticles: Synthesis and Surface Modifications, CRC Press, Boca-Raton, 2010, 26-60.
[52] Fujibayashi T., Okubo M.: Langmuir, 2007, 23, 7958. https://doi.org/10.1021/la7007842.
https://doi.org/10.1021/la7007842
[53] Voronov S., Tokarev V., Datsyuk V., Kozar M.: The 37th General Meeting of the German Colloid Society, German, Dresden 1996, 189. https://doi.org/10.1007/BFb0114468.
https://doi.org/10.1007/BFb0114468
[54] Tokarev V., Voronov S., Adler H.-J., et al.: Macromol. Symp., 2002 ,187, 155. https://doi.org/10.1002/1521-3900(200209)187:1<155::AID-MASY155>3.0.CO;2-H.
https://doi.org/10.1002/1521-3900(200209)187:1<155::AID-MASY155>3.0.CO;2-H
[55] Voronov S., Tokarev V., Datsyuk V., et al.: J. Appl. Polym. Sci., 2000, 76, 1228. https://doi.org/10.1002/(SICI)1097-4628(20000523)76:8<1228::AID-APP3>3.0.CO;2-8.
https://doi.org/10.1002/(SICI)1097-4628(20000523)76:8<1228::AID-APP3>3.0.CO;2-8
[56] Shevchuk O., Tokarev V., Bukartyk N., Voronov S.: Macromol. Symp., 2007, 254, 260. https://doi.org/10.1002/masy.200750839.
https://doi.org/10.1002/masy.200750839
[57] Kagawa Y., Minami H., Okubo M., Zhou J.: Polymer, 2005, 46, 1045. https://doi.org/10.1016/j.polymer.2004.11.040.
https://doi.org/10.1016/j.polymer.2004.11.040
[58] Kitayama Y., Kagawa Y., Minami H.,.Okubo M.: Langmuir, 2010, 26, 7029. https://doi.org/10.1021/la904296h.
https://doi.org/10.1021/la904296h
[59] Jhaveri S., Koylu D., Maschke D., Carter K.: J. Polym. Sci. Part A., 2007, 45, 1575. https://dx.doi.org/10.1002/pola.21977.
https://doi.org/10.1002/pola.21977
[60] Tang D., Yuan R., Chai Y., An H.: Adv. Funct. Mater., 2007, 17, 976. https://doi.org/10.1002/adfm.200600462.
https://doi.org/10.1002/adfm.200600462
[61] Gai L., Li Z., Hou Y.et al.: J. Phys. D: Appl. Phys., 2010, 43(44), 445001. https://doi.org/10.1088/0022-3727/43/44/445001.
https://doi.org/10.1088/0022-3727/43/44/445001
[62] Wang H., Zhang Y., Yan B. et al.: Clin. Chem., 2006, 52, 2065. https://doi.org/10.1373/clinchem.2006.071555.
https://doi.org/10.1373/clinchem.2006.071555
[63] Shtykov S., Rusanova T.: Russ. J. Gen. Chem., 2008, 78, 2521. https://doi.org/10.1134/S1070363208120323.
https://doi.org/10.1134/S1070363208120323
[64] Aslan K., Wu M., Lakowicz J., Geddes C.: J. Am. Chem. Soc., 2007, 129, 1524. https://doi.org/10.1021/ja0680820.
https://doi.org/10.1021/ja0680820
[65] Shao M., Ning F., Zhao J. et al.: J. Am. Chem. Soc., 2012, 134, 1071. https://doi.org/10.1021/ja2086323.
https://doi.org/10.1021/ja2086323
[66] Liu X., Knauer M., Ivleva N. et al.: Anal. Chem., 2010, 82, 441. https://doi.org/10.1021/ac902573p.
https://doi.org/10.1021/ac902573p
[67] Vaculik P.: Khimiya Monomerov. Inostrannaya literatura, Moskva 1960.
[68] Moldavsky B.; Kernos Y.: Maleyinovyi Anhidrid i Maleyinovaya Kislota. Khimiya, Leningrad 1976.
[69] Hevus O., Kohut A., Fleychuk R. et. al.: Macromol. Symp., 2007, 117. https://doi.org/10.1002/masy.200750818.
https://doi.org/10.1002/masy.200750818
[70] Vylenskaya M., Karamov D., Sorokin E. et al.: Khimicheskaya Promyslennost, 1979, 7, 15.
[71] Abramson A.: Povercnosno-Activnye Soyedineniya. Svoystva i Priminenia, Khimia, Leningrad 1981.
[72] Zaichenko A., Mitina N., Kovbuz M. et al.: J. Polym. Sci. A., 2000, 38, 516. https://doi.org/10.1002/(SICI)1099-0518(20000201)38:3<516::AID-POLA18>3.0.CO;2-R.
https://doi.org/10.1002/(SICI)1099-0518(20000201)38:3<516::AID-POLA18>3.0.CO;2-R
[73] Zaichenko A., Voronov S., Shevchuk O. et al.: J. Appl. Polym. Sci., 1998, 67, 1061. https://doi.org/10.1002/(SICI)1097-4628(19980207)67:6<1061::AID-APP13>3.0.CO;2-3.
https://doi.org/10.1002/(SICI)1097-4628(19980207)67:6<1061::AID-APP13>3.0.CO;2-3
[74] Cherpak V., Stakhira P., Khomyak S. et al.: Opt. Mater., 2011, 33, 1727. https://doi.org/10.1016/j.optmat.2011.05.034.
https://doi.org/10.1016/j.optmat.2011.05.034
[75] Bagdasarian Kh.: Theory of Free Radical Polymerization, Israel Program for Scientific Translations, Jerusalem 1968.
[76] Gladyshev G., Popov V.: Radialnaya Polimerizaciya pri Hlubokikh Stadiyah Prevrashcheniya. Nauka, Moskva 1974.
[77] Toroptseva A., Belogorodskaya K., Bondarenko V.: Laboratorniy Praktikum po Khimii i Technolohii Vysokomoleculyarnykh Soyedineniy. Khimiya, Leningrad 1972 .
[78] Neiman R. (Ed.): Prakticheskie Raboty po Koloidnoi Khimii. Coloidnaya Khimia Lateksov i Poverhnosno-Activnykh Soedineniy. Vyshaia shkola, Moskva 1972.
[79] Zaichenko A., Mitina N., Kovbuz M. et al.: Macromol. Symp., 2001, 164, 47. https//doi.org/10.1002/1521-3900(200102)164:1<47::AID-MASY47>3.0.CO;2-F.
https://doi.org/10.1002/1521-3900(200102)164:1<47::AID-MASY47>3.0.CO;2-F
[80] Kohut A, Hevus O., Voronov S.: J. Appl. Pol. Sci., 2004, 93, 310. https//doi.org/10.1002/app.20456.
https://doi.org/10.1002/app.20456
[81] Smith B.: Infrared Spectral Interpretation: A Systematic Approach, CRC Press, Boca-Raton 1999.
[82] Eliseeva V.: Polimernye Dispersii, Khimia, Moskva 1980.