Melamine sulfate (Si-MelaSO4H) was prepared by treated melamine, which was immobilized onto silica (Si-Mela) with 0.05 M sulfuric acid at room temperature. The TGA confirmed that the thermal stability could reach 473 K. The XRD pattern showed that in some patterns there were sharp peaks and in other pattern a broad band was shown, which indicated that the surface is a mix of crystalline and non-crystalline nature. The Si-MelaSO4H was used successfully in the preparation of Schiff bases and its derivatives. The optimum conditions of the Si-MelaSO4H were found to be 0.25 g catalyst mass at 343 K for 9 h. The catalyst was reused several times without loss of catalytic activity.
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