The catalytic effect of ruthenium chloride on the outer sphere electron transfer of hexacyanoferrate(II) by periodate ion in aqueous alkaline medium has been effectively employed to determine ruthenium(III) at micro level. The optimum reaction condition has been established and fixed time procedure is adopted. A linear relationship between changes in absorbance and added Ru(III) concentration has been utilized for the trace level determination of Ru(III). The results reveal that the addition of interfering ions (up to 71 times higher concentration of Ru) does not have significant effect on the catalytic activity of Ru(III) on oxidation of hexacyanoferrate(II) by periodate ion. Polyaminocarboxylates (HEDTA, EDTA and IDA) suppress its catalytic power to maximum, if tolerance limit is more than 14.29 times. Due to the reproducibility, stability and selectivity, this method can also be quantitatively applied in different types of water samples for determination of ruthenium(III) at micro level.
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