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  3. Volume 14, Number 2, 2020
  4. A Methodology Study of Hydrophosphonylation of Aldehydes Derivatives with H6P2W18O62•14H2O as a Catalyst

A Methodology Study of Hydrophosphonylation of Aldehydes Derivatives with H6P2W18O62•14H2O as a Catalyst

JCCT.
2020;
Volume 14, Number 2
: pp. 154 - 160
https://doi.org/10.23939/chcht14.02.154
Authors:
  1. Zineb Aouf
  2. Sara Boughaba
  3. Ouahiba Bechiri
  4. Nour-Eddine Aouf
1
Laboratory of Applied Organic Chemistry, Bioorganic Chemistry Group, Sciences Faculty, Chemistry Department, Badji Mokhtar-Annaba University
2
Laboratory of Applied Organic Chemistry, Bioorganic Chemistry Group, Sciences Faculty, Chemistry Department, Badji Mokhtar-Annaba University
3
Laboratory of Environmental Engineering, Department of Process Engineering, Faculty of Engineering, Badji Mokhtar Annaba University
4
Laboratory of Applied Organic Chemistry, Bioorganic Chemistry Group, Sciences Faculty, Chemistry Department, Badji Mokhtar-Annaba University

A catalytic process for hydrophosphonylation of aldehydes with H6P2W18O62•14H2O has been developed in this paper. Various aldehydes were reacted with diethylphosphite in the presence of 1 % of heteropolyacids (HPAs) as a catalyst to generate the α-hydroxyphosphonates. All the synthesized compounds were systematically characterized by IR, 1H NMR, 13C NMR, and 31P NMR. Simple and mild method, short reaction time, solvent-free conditions, availability and reusability of the catalyst are the main advantages of this procedure.

aldehyde
diethylphosphite
Pudovik reaction
α-hydroxyphosphonate
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