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  3. Volume 15, Number 4, 2021
  4. Characterization and Properties of Titanium(IV) Oxide, Synthesized by Different Routes

Characterization and Properties of Titanium(IV) Oxide, Synthesized by Different Routes

JCCT.
2021;
Volume 15, Number 4
: pp. 465-474
https://doi.org/10.23939/chcht15.04.465
Authors:
  1. Tetiana Dontsova
  2. Ahmad Hosseini-Bandegharaei
1
Department of Technology of Inorganic Substances, Water Purification and General Chemical Technology, National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”
2
Department of Environmental Health Engineering, Faculty of Health, Sabzevar University of Medical Sciences, Department of Engineering, Kashmar Branch, Islamic Azad University

The article considers the influence of precursor type and sol-gel synthesis conditions of TiO2 on its properties. The obtained TiO2 samples were characterized by X-ray diffraction methods, electron microscopy, as a result of which it was found that all the obtained TiO2 powders have the crystallite size in a nanorange of 2.5–17 nm. It was shown that sorption-photocatalytic properties of TiO2 significantly depend on a phase composition, surface acidity, specific surface area and porosity. It was found that the amorphous TiO2 has improved adsorption properties, while crystalline TiO2 is characterized by enhanced photocatalytic properties. Determined acidic nature of the TiO2 surface explains the better sorption and photocatalysis relative to the cationic dye.

titanium(IV) oxide
sol-gel method
structural-adsorption characteristics
sorption
photocatalysis
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