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  2. All Volumes and Issues
  3. Volume 17, Number 1, 2023
  4. Activation of Mo2B Catalyst in the Epoxidation Reaction of α-Ethylallyl Ethyl Acrylate with tert-Butyl Hydroperoxide

Activation of Mo2B Catalyst in the Epoxidation Reaction of α-Ethylallyl Ethyl Acrylate with tert-Butyl Hydroperoxide

JCCT.
2023;
Volume 17, Number 1
: pp. 18 - 23
https://doi.org/10.23939/chcht17.01.018
Authors:
  1. Zoryana Komarenska
  2. Lilianna Oliynyk
  3. Oksana Makota
1
Lviv Polytechnic National University
2
Lviv Polytechnic National University
3
Lviv Polytechnic National University

The regularities of Mo2B catalyst activation in the epoxidation reaction of $\alpha$-ethylallyl ethyl acrylate with tert-butyl hydroperoxide have been studied. It has been shown that the catalyst activation process is described by the Avrami-Erofeev topokinetic equation and  includes two successive stages – the nucleation and formation of a new phase active in the epoxidation reaction. The forma- tion of epoxy only occurs in the presence of the activated form of the catalyst. The effective and topochemical process constants have been calculated.

oxidation
kinetic laws
catalyst
olefin.α
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