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  4. INFLUENCE OF HYDROPEROXIDE EPOXIDATION REACTION CONDITIONS OF OCTEN-1 ON THE PROCESS OF Mo2B ACTIVATION AND ON THE SELECTIVITY OF EPOXIDE FORMATION

INFLUENCE OF HYDROPEROXIDE EPOXIDATION REACTION CONDITIONS OF OCTEN-1 ON THE PROCESS OF Mo2B ACTIVATION AND ON THE SELECTIVITY OF EPOXIDE FORMATION

CTAS.
2020;
Volume 3, Number 2
: 7-10
https://doi.org/10.23939/ctas2020.02.007
Authors:
  1. Zoryana Komarenska
  2. M. V. Nykypanchuk
  3. Oksana Makota
  4. Lilianna Oliynyk
1
Lviv Polytechnic National University
2
Lviv Polytechnic National University
3
Lviv Polytechnic National University
4
Lviv Polytechnic National University

A study of the process of activation of molybdenumboride catalyst in the reaction of epoxidation of octene-1 with tert-butyl hydroperoxide and the effect on this process of the initial concentration of octene-1, tert-butyl hydroperoxide and the amount of catalyst in the reaction mixture. As well as reaction products (tert-butyl alcohol and epoxy). It is shown that over time a new amorphous phase is formed on the surface of Mo2B, which actually catalyzes the epoxidation reaction of octene-1 with tert-butyl hydroperoxide. The formation of this phase is the reason for the acceleration of the rate of consumption of hydroperoxide and the selectivity of the formation of epoxide over time.

oxidation
kinetic laws
catalyst
Olefin

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doi: 10.1134 / S0023158414020062.

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