The Experimental and Theoretical Estimation of Interfacial Layer Thickness in Elastomeric Nanocomposites

Автори: 
Georgiy Kozlov, Yuriy Yanovskii and Gennady Zaikov

The interfacial layer thickness and its elasticity modulus were determined experimentally for particulate-filled polymer nanocomposite. It has been found out that elasticity modulus of interfacial layer is 5 times greater than corresponding characteristic for bulk polymer matrix. It has been shown that the theoretical calculation of interfacial layer thickness within the frameworks of fractal model corresponds well to experimental data.

[1] Kozlov G., Burya A. and Lipatov Yu.: Mekhanika Kompozitnykh Materialov, 2006, 42, 797.
[2] Kornev Yu., Yumashev O., Zhogin V. et al.: Kauchuk i Rezina, 2008, 6, 18.
[3] Mikitaev A., Kozlov G. and Zaikov G.: Polymer Nanocomposites: the Variety of Structural Forms and Applications. Nova Science Publishers, Inc., New York 2008.
[4] Oliver W. and Pharr G.: J. Mater. Res., 1992, 7, 1564.
[5] Lazorenko M., Badlyuk S., Rokochii N. and Shut N.: Kauchuk i Rezina, 1988, 11, 17.
[6] Kozlov G., Yanovskii Yu. and Lipatov Yu.: Mekhanika Kompozitsionnykh Materialov i Konstruktsii, 2002, 8, 111.
[7] Kozlov G., Yanovskii Yu. and Zaikov G.: Structure and Properties of Particulate-Filled Polymer Composites: the Fractal Analysis. Nova Science Publishers, Inc., New York 2010.
[8] Hentschel H. and Deutch J.: Phys. Rev. A, 1984, 29, 1609.
[9] Kozlov G. and Zaikov G.: Structure of the Polymer Amorphous State. Brill Academic Publishers, Utrecht, Boston 2004.
[10] Wu S.: J. Polymer Sci. B, 1989, 27, 723.
[11] Aharoni S.: Macromolecules, 1983, 16, 1722.
[12] Budtov V.: Fizicheskaya Khimiya Polymernyh Rastvorov. Khimiya, Sankt-Peterburg 1992.
[13] Aharoni S.:Macromolecules, 1985, 18, 2624.
[14] Bobryshev A., Kozomazov V., Babin L. and Solomatov V.: Sinergetika Kompositsionnyh Materialov., NPO ORIUS, Lipetsk 1994.
[15] Kozlov G., Yanovskii Yu. and Karnet Yu.: Mekhanika Kompozitsionnykh Materialov i Konstruktsii, 2005, 11, 446.
[16] Sheng N., Boyce M., Parks D. et al.: Polymer, 2004, 45, 487.