The analysis of charge transfer processes in the electrical conducting solid polymer systems has been carried out. The processes in these systems are divided to two types. The first type is the process of charge transfer between electrodes and particles while the second one – the process of the charge transfer between conductive particles. The description of medium is carried out using Green temperature functions of polarization operators for the molecular medium. It permits taking into account the effects of frequency and space dispersion. The analytical expressions for kinetic parameters of the charge transfer processes from electrodes to particles and between particles in condensed matter have been obtained. The comparison of the general theoretical dependence of the current in electric conducting polymer composites (ECPC) on the average distance between conducting particles with analogical dependence for some real ECPC are presented in the paper.
[1] Norman R.: Conductive Rubber and Plastics. Elsevier, Amsterdam 1970.
[2] Bendikov,M., Wude F. and Perepichka D.: Chem. Rev., 2004, 104, 4891.
[3] Zhu D., Bin Y. and Matsuo M.: J. Polym. Sci. B, 2007, 45, 1037.
[4] Aneli J., Zaikov G. and Mukbaniani O.: Mol. Crist. Liq. Cryst., 2012, 554, 167.
[5] Aneli J., Khananashvili L. and Zaikov G.: Structuring and Conductivity of Polymer Composites, Novo-Sci. Publ., New-York 1998.
[6] Sheng S.: Phys.Rev. B., 1980, 21, 2180.
[7] Shklowskii B. and Efros А.: Electronnye Svoistva Legirovannykh Poluprovodnikov. Nauka, Moskwa 1979.
[8] Bin J., Kitanake M., Zhu D. and MatsuoM.: Macromolecules, 2003, 36, 6213.
[9] Bin J., Xu C. and Matsuo M.: Carbon, 2002, 40, 195.
[10] Benguigu L., Jakubovich J. and Narkis M.: J. Pol. Sci. B, 1987, 25, 127.
[11] Balberg I.: Carbon, 2002, 40, 139.
[12] Heaney M.: Physica A, 1997, 241, 296.
[13] Beaucage G., Rane S., Shaffer D. et al.: J. Polym. Sci. B, 1999, 37, 1105.
[14] Lee B.: Polym. Eng. Sci., 1992, 32, 36.
[15] Bridge W., Folkes B. and Wood B.: J. Phys. D., 1990, 23, 890.
[16] Wesslin B.: Macromol. Chem., 1984, 185, 1265.
[17] Zainutdinov A., Kasimov A. and Magrupov A.: Pisma v Zh. Experim. i Teoret. Phiziki, 1992, 18, 29.
[18] Strumplen R. and Glatz-Reichenbach J.: J. Electroceramics, 1999, 3, 329.
[19] Thongruang W., Balik C. and Spontak R.: J. Polymer, 2002, 43, 2279.
[20] Abrikosov A., Gorkov L. and Dzialoshinskii I.: Methods of Quantum Field Theory in Statistical Physics. Dover, New-York 1975.
[21] March N. and Young S.: The Many Body Problem in Quantum Mechanics, Dover, New-York 1995.
[22] Dogonadze R. and Marsagishvili T.: Chemical Physics of Solvation. Part A. Elsevier, Amsterdam 1985.
[23] Dogonadze R.,.Kuznetsov A. and Marsagishvili T.: Electrochimica Acta, 1980, 1, 156.