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  3. Volume 7, Number 3, 2013
  4. Research of Influence of the Nature of Metal on the Mechanism of Synthesis of Polyvinylpyrrolidone Metal Copolymers

Research of Influence of the Nature of Metal on the Mechanism of Synthesis of Polyvinylpyrrolidone Metal Copolymers

JCCT.
2013;
Volume 7, Number 3
Authors: 

Oleh Suberlyak, Oleksandr Grytsenko, Krystyna Hischak and Natalia Hnatchuk

The influence of the metal fine filler nature on the polymerization mechanism of polyvinylpyrrolidone-methacrylate compositions in the presence and without iron(II) sulphate has been determined. The catalysis mechanism has been confirmed via complexation with charge transfer between the initial composition components. The metal activating effect increases with the increase of its negative electrochemical potential.

polyvinylpyrrolidone
kinetics
complexation
catalysis
metal-hydrogels.

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