Influence of Bi3+ Ions on Kinetics of Lead Dioxide Electrodeposition from Methanesulfonate Electrolytes

Received: September 25, 2012
Revised: December 03, 2012
Accepted: May 30, 2013
Автори: 
Olesia Shmychkova, Amina Magomedova, Dmitriy Girenko, Tatiana Luk’yanenko and Alexander Velichenko

Influence of bismuth ions on kinetics of lead dioxide electrodeposition from methanesulfonate electrolytes on Pt-electrode was studied. Experimental results are interpreted to be consistent with the mechanism proposed previously for lead dioxide electrodeposition in literature. The presence of bismuth ions in the electrodeposition solution causes decreasing rate constants of lead dioxide formation due to additive adsorption.

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