цеоліт

The purpose of this work was to study the process of adsorption of phosphate on natural and synthesized sorbents, such as aluminosilicates. The sorption properties of natural zeolite for phosphate under static and dynamic conditions were investigated. The zeolite on the basis of the coal fly ash of Dobrotvorskaya heat power plant was synthesized and modified. The equilibrium values of adsorption capacity were determined, and the corresponding isotherms were constructed at a temperature of 20° C. The kinetics of adsorption under mechanical mixing conditions was investigated.

The hydrogen adsorption and desorption isotherms of multiwalled carbon nanotube sample (MWCNT), an iron loaded multiwalled carbon nanotube (Fe_MWCNT), two zeolites (Na_Y_Zeo and NH4_Y_Zeo) and MCM-41 were measured at 77 K and atmospheric pressure by using the volumetric adsorption apparatus. The adsorption data were evaluated by several isotherm equations such as Langmuir, Freundlich, Temkin and Harkins-Jura isotherm models but were best described by the Freundlich isotherm model as it gave the highest correlation.

The statics and kinetics of albumin adsorption on natural zeolite of clinoptilolite structure have been investigated. The basic characteristics of zeolite have been determined. The method of albumin in a solution analysis was given. An isotherm of albumin adsorption was plotted and the Langmuir equation describing this isotherm was given. The presence of an external and pore diffusion adsorption mechanism has been experimentally established during the study of kinetics in a machine with mechanical stirring.

Zeolites were added to polyethersulphone (PES) membranes in order to enhance their capability of attracting creatinine. Zeolite was blended with PES by varying its doping concentration and time, and the mechanical properties of the resulting hollow fibre membranes produced under optimal concentration were characterised. The values of tensile stress, tensile strain and Young’s modulus, as well as the flux and rejection of the membranes were determined.

The results of research of the chemical activation process of clinoptilolite from Sokirnytskyi field are shown. As a result of the research, the effectiveness of the influence on zeolite hydrochloric and sulfuric acids are compared. It should be noted that the advantage is on the side of hydrochloric acid. It was established that the increase in the concentration of sulfuric acid and the time of zeolite processing leads only to the increase in the content of the amorphous phase.

The kinetics of copper ions adsorption by natural zeolite has been investigated in the apparatus with mechanical stirrer. The presence of external diffusion and pore diffusion area was established. For the external diffusive area, the dependence of mass transfer coefficient on stirrer rotation speed was confirmed; the dependence was described using a criterial equation. For the pore diffusion area, the equation is adduced by means of which the effective coefficient of pore diffusion was calculated.

It was established that natural and Ca modified zeolite inhibit steel corrosion in the medium of low acid rain. The Ca-containing zeolite inhibit the steel corrosion in the most effective way. The protective effectiveness of the alkyd coatings filled with zeolites can be placed in the following order:  unmodified < with natural zeolite < with Ca-containing zeolite.  Встановлено, що природний та модифікований кальцієм цеоліти інгібують корозію сталі в середовищі слабкокислих дощових опадів. Найефективніше інгібує корозію сталі Ca-вмісний цеоліт.

The features of adipic acid esterification with 1-butanol in the presence of aluminosilicates activated with sulfuric acid as a catalyst have been studied. The optimal process conditions have been determined. The influence of a heterogeneous catalyst nature on the esterification proceeding has been defined. Досліджено закономірності естерифікації адипінової кислоти 1-бутанолом у при- сутності активованих сульфатною кислотою алюмосилікатів як каталізаторів. Визначено оптимальні умови процесу. Встановлено вплив природи гетерогенного каталізатора на перебіг естерифікації. 

Adsorption of surfactants on varios types of adsorbent was experimentally investigated. Generalization of the obtained results of research and calculation data was carried out. Експериментально досліджено адсорбцію ПАР на різних типах сорбентів. Проведено узагальнення отриманих результатів досліджень та розрахункових даних.