thiosulfoesters

The acylation of aminogroup of alkyl S-esters 4-aminobenzenthiosulfoacid with cyanurchloride was investigated. Series of esters with triazine fragment were synthesized and characterized by elemental analysis, 1H NMR and IR spectroscopy. The growth-regulative activity of the synthesized compounds was researched. Some appropriate effect of thiosulfoesters structure upon their growth-regulative activity was determined.

Cyclic imides are privileged pharmacophores and important building blocks for the synthesis drugs, agrochemicals, advanced materials and polymers. A number of valuable natural products contain an imid fragment in their structure, in particular, Migrastatin, lamprolobin, julocrotine, cladoniamide A.

The nucleophilic substitution of halogens in 2,3-dichlor-1,4-naphtoquinone with salts of aliphatic, aromatic and heterocyclic thiosulfonic acids have been researched. 
Досліджено нуклеофільне заміщення галогенів у 2,3-дихлор-1,4-нафтохіноні солями аліфатичних, ароматичних та гетероциклічних тіосульфокислот. 
 

The novel sugar-containing thiosulfoesters were prepared from the natural compound – glycidylgalactose. The synthesis techniques of arylsulfonic acids sugar-containing thioesters were developed and worked out on the basis of the model compound – 2-butoxymethylthiirane. 
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Синтезовано нові сахаридовмісні тіосульфоестери на основі сполуки природного походження – гліцидилгалактози. Методики синтезу сахаридовмісних тіоестерів аренсульфонових кислот розроблено та відпрацьовано на основі модельної сполуки – 2-бутоксиметилтіїрану.