Polymers as Natural Nanocomposites. 3. The Geometry of Intercomponent Interactions

Authors: 

Musa Bashorov, Georgiy Kozlov, Gennady Zaikov and Abdulakh Mikitaev

The treatment of amorphous glassy polymers as natural nanocomposites is proposed. It has been shown that the geometry of intercomponent interactions nanoclusters – loosely-packed matrix defines adhesion level between the indicated components of natural nanocomposites. Since nanoclusters – loosely-packed matrix contact is realized over cylindrical surface of the first ones then the larger the indicated surface area the higher the intercomponent adhesion level.

[1] Ivanchev S. and Ozerin A.: Vysokomol. Soed. B, 2006, 48, 1531.
[2] Malamatov A., Kozlov G. and Mikitaev M.: Mekhanismy uprochneniya polimernych nanokompozitov. Izd-vo RKhTU Mendeleeva, Moskwa 2006.
[3] Kozlov G. and Zaikov G.: Structure of the polymer amorphous state. Brill Academic Publishers, Utrecht-Boston 2004.
[4] Lipatov Yu.: Mezhfaznye yavleniya v polimerakh. Naukova Dumka, Kiev 1980.
[5] Tugov I. and Shaulov A.: Vysokomol. Soed. B, 1990, 32, 527.
[6] Kozlov G. and Aloev V.: Teoriya perkolyatsii v fiziko-khimii polimerov. Polygraphservis i T., Nal’chik 2005.
[7] Kalinchev E. and Sakovtseva M.: Svoistva i pererabotka termoplastov. Khimiya, Leningrad 1983.
[8] Leidner J. and Woodhams R.: J. Appl. Polymer Sci., 1974, 18, 1639.
[9] Ahmed S. and Jones F.: J. Mater. Sci., 1990, 25, 4933.
[10] Novikov V., Kozlov G. and Bur’yan O.: Mekhanika Kompositnykh Materialov, 2000, 36, 3.
[11] Stanley H.: [in:] Pietronero L. and Tosatti E. (eds.) Fractals in Physics. North-Holland, Amsterdam, Oxford, New York, Tokyo 1986, 463-477.
[12] Kozlov G., Shogenov V. and Mikitaev A.: Inzhenerno-Fizicheskiy Zh., 1998, 71, 1012.
[13] Aharoni S.: Macromolecules, 1985, 18, 2624.
[14] Bobryshev A., Kozomazov V., Babin L. and Solomatov V.: Sinergetika kompozitnykh materialov. NPO ORIUS, Lipetsk 1994.
[15] Wu S.: J. Polymer Sci. B, 1989, 27, 723.
[16] Aharoni S.: Macromolecules, 1983, 19, 1722.
[17] Budtov V.: Fizicheskaya khimiya rastvorov polimerov. Khimiya, Sankt-Peterburg 1992.
[18] Kozlov G. and Novikov V.: Sinergetika i fraktal’nyi analiz schitykh polimerov. Klassika, Moskwa 1998.
[19] Balankin A.: Sinergetika deformiruemogo tela. Izd-vo Ministerstva oborony SSSR, Moskwa 1991.
[20] Kozlov G. and Sanditov D.: Angarmonicheskie efekty i fiziko-mechanicheskie svoistva polimerov. Nauka, Novosibirsk 1994.