The oligomerization in solution and suspension oligomerization of the fraction C9 of liquid by-products of pyrolysis of diesel fuel is initiated by 2- (third-butylperoxymethylamineo) acetate acid have been studied. The nature of the effect of oligomerization, the concentration of the initiator, the temperature and duration of the reaction to the output and the physicochemical characteristics of the obtained oligomers were clarified. The optimal technological parameters of the process of oligomerization of the fraction C9 were selected. Relatively peculiarities of the course of suspension oligomerization and oligomerization in the solution of the fraction C9.
1. Zongyan, F. (2006). Application and Production of C9 Petroleum Resin [J]. Petrochemical Industry Technology, 1.
2. Zohuriaan-Mehr, M. J., & Omidian, H. (2000). Petroleum Resins: An Overview. Journal of Macromolecular Science, Part C, 40(1), 23-49.
https://doi.org/10.1081/MC-100100577
3. Mildenberg, R., Zander, M., & Collin, G. (2008). Hydrocarbon resins. John Wiley & Sons.
4. Kurta, S. A. (2009). Khimiia i tekhnolohiia khlororhanichnykh spoluk.
5. Rahmatpour, A., & Ghasemi Meymandi, M. (2021). Large-Scale Production of C9 Aromatic Hydrocarbon Resin from the Cracked-Petroleum-Derived C9 Fraction: Chemistry, Scalability, and Techno-economic Analysis. Organic Process Research & Development, 25(1), 120-135.
https://doi.org/10.1021/acs.oprd.0c00474
6. Grynyshyn, O., Bratychak, M., Krynytskiy V., & Donchak, V. (2008). Petroleum resins for bitumens modification. Chemistry & Chemical Technology, 2(1), 47-53.
https://doi.org/10.23939/chcht02.01.047
7. Yang, J., Cao, Z., & Qi, Y. (2014). Polymerization of C9fraction from ethylene cracking catalyzed by Al3+-loaded styrenic cation exchange resin. Asian Journal of Chemistry, 26(19).
https://doi.org/10.14233/ajchem.2014.17387
8. Gnativ, Z., Nylukyshyn, I., Pikh, Z., Voronchak, T., & Rypka, A. (2014). Catalytic cooligomerization of styrene and dicyclopentadiene: yield and properties dependence on reaction mixture composition.
https://doi.org/10.23939/chcht08.02.165
9. Kurtash, Yu. A., Kochubei, V. V., Subtelnyi, R. O., & Dziniak, B. O. (2009). Oderzhannia NPS z vykorystanniam olihoperoksydiv. Voprosy khymyy y khymycheskoi tekhnolohyy, 4, 114-118.
10. Dziniak, B. O., & Mahorivska, H. Ya. (2003). Initsiiovana makroperoksysylanamy olihomeryzatsiia fraktsii S9 pirolizu dyzelnoho palyva. Voprosy khymyy y khymycheskoi tekhnolohyy, 1, 76-80.
11. Orobchuk, O M, Fuch, U V, Subtelnyi, R O, & Dziniak, B O. (2014). Optymizatsiia protsesu dyspersiinoi koolihomeryzatsii fraktsii C9 shliakhom pobudovy matematychnoi modeli. Visnyk Natsionalnoho universytetu "Lvivska politekhnika". Khimiia, tekhnolohiia rechovyn ta yikh zastosuvannia., (787), 153-157.
12. Orobchuk, O. M., Subtelnyi, R. O., & Dziniak, B. O. (2014). Vyvchennia vplyvu dozuvannia initsiatora na protses suspenziinoi koolihomeryzatsii vuhlevodnevoi fraktsii. Eastern-European Journal of Enterprise Technologies, 4(6(70)), Art. 6(70).
13. Dzumedzei, M. V., Kucher, R. V., Turovskyi, A. A., & Koshovskyi, B. I. (1971). Doslidzhennia kinetyky termichnoho rozpadu azotumisnykh perekysnykh spoluk z tret-alkilnym radykalom. Ukraynskyi khymycheskyi zhurnal, 39, 1142-1145.
14. Butylyna, N. A., Dybryvnyi, V. N., & Kochubei, V. V. (2003). Fyzyko-khymycheskye svoistva tret-butylperekysy-dyetylamynometana y tret-butylperekysypyperydylmetana., 40-42.
15. Subtelnyy, R., Zhuravskyi, Y., Kichura, D., & Dzinyak, B. (2022). Oligomerization of S9 hydrocarbon fraction initiated by amino peroxides with cyclic substitute. Eastern-European Journal of Enterprise Technologies, 3(6-117), 23-31.
https://doi.org/10.15587/1729-4061.2022.259892
16. Turovskyi, A. A., & Dzumudzei, M. V. (1973). Pro kinetyku peredachi lantsiuha cherez azotvmisni perekysy z tret-butylnym radykalom pry polimeryzatsii styrolu v masi. Dopovidi NAN Ukrainy, 5, 1106-1108.