Густина, надлишковий об’єм і парціальні мольні об’єми розчинів бутилметакрилату в деяких органічних розчинниках

Автори:
1
Lviv Polytechnic National University

Визначено концентраційну залежність густини і надлишкового об’єму бінарних систем бутилметакрилату в ацетонітрилі, гексані, бензені, 1,2-дихлоретані й оцтовій кислоті за 293 K й атмосферного тиску з використанням пікнометричного методу. Визначені значення надлишкового об’єму апроксимовані поліномами. Розраховано значення парціальних мольних об’ємів досліджених розчинів.

  1. George, J.; Sastry, N.V.; Prasad, D.H.L. Excess Molar Enthalpies and Excess Molar Volumes of Methyl Methacrylate + Benzene, + Toluene, + p-Xylene, + Cyclohexane and + Aliphatic Diethers (Diethyl, Diisopropyl and Dibutyl). Fluid Phase Equilib. 2003, 214, 39-51. https://doi.org/10.1016/S0378-3812(03)00312-1
  2. Peralta, R.D.; Infante, R.; Cortez, G.; Wisniak, J. Density and other Thermodynamic Properties of the Binary Systems of tetrahydrofuran + Ethenyl Ethanoate, Methacrylic Acid, Butyl Methacrylate, and Allyl Methacrylate at 298.15 K. Phys. Chem. Liquids 2005, 43, 249-259. https://doi.org/10.1080/00319100500061274
  3. Wisniak, J.; Peralta, R.D.; Infante, R.; Cortez, G.; López, R.G. Densities, Isobaric Thermal Compressibilities and Derived Thermodynamic Properties of the Binary Systems of Cyclohexane with allyl Methacrylate, Butyl Methacrylate, Methacrylic Acid, and Vinyl Acetate at T = (298.15 and 308.15) K. Thermochim. Acta 2005, 437, 1-6. https://doi.org/10.1016/j.tca.2005.06.007
  4. Wisniak, J.; Cortez, G.; Peralta, R.D.; Infante, R.; Elizalde, L.E. Some Thermodynamic Properties of the Binary Systems of Toluene with Butyl Methacrylate, Allyl Methacrylate, Methacrylic Acid and Vinyl Acetate at 20, 30 and 40°C. J. Solution Chem. 2007, 36, 997-1022. https://doi.org/10.1007/s10953-007-9165-y
  5. Peralta, R.D.; Infante, R.; Cortez, G.; Wisniak, J. Densities and Derived Thermodynamic Properties of the Binary Systems of Benzene with Butyl Methacrylate, Allyl Methacrylate, Methacrylic Acid, and Vinyl Acetate at 298.15 K. Chem. Eng. Commun. 2007, 194, 635-647. https://doi.org/10.1080/00986440600992701
  6. Wisniak, J.; Cortez, G.; Peralta, R.D.; Infante, R.; Elizalde, L.E.; Amaro, T.A.; García, O.; Soto, H. Volumetric Properties of the Ternary System Dimethyl Carbonate + Butyl Methacrylate + Allyl Methacrylate and Its Binary Butyl Methacrylate + Allyl Methacrylate at 293.15 K and p=101.325 kPa. J Solut. Chem. 2012, 41, 1631-1648. https://doi.org/10.1007/s10953-012-9892-6
  7. Sergeev, V.V.; Dibrivnyi, V.N.; Van-Chin-Syan, Yu.Ya. Heat of Mixing of Acrylic Acid with Certain Organic Solvents. Russ. J. Appl. Chem. 2011, 84, 898-901. https://doi.org/10.1134/S1070427211050284
  8. Sergeev, V.V.; Van-Chin-Syan, Yu.Ya. Heats of Mixing Butylacrylate with Certain Organic Solvents. Russ. J. Appl. Chem. 2012, 85, 689-691. https://doi.org/10.1134/S107042721204028
  9. Sergeev, V. V.; Dibrivnyi, V.N.; Van- Chin-Syan, Yu.Ya. Density, Partial Molar Volume, and Excess Volume of Solutions of Acrylic Acid in Acetonitrile, 1,2-Dichloroethane, Hexane, and Benzene at 293 K. Russ. J. Gen. Chem. 2012, 82, 202-205. https://doi.org/10.1134/S1070363212020065
  10. Serheyev, V. Enthalpies of Mixing Methylmethacrylate with Some Organic Solvents. Chem. Chem. Technol. 2012, 6, 15-18. https://doi.org/10.23939/chcht06.01.015
  11. [Sergeev, V.V.; Van-Chin-Syan, Yu.Ya. Density, Partial, and Excess Volumes of Solutions of Methacrylic Acid in Organic Solvents at 293 K. Russ. J. Phys. Chem. A. 2015, 89, 406-410. https://doi.org/10.1134/S0036024415030279
  12. Serheyev, V. Enthalpies of Mixing of the Laurylmethacrylate with Some Organic Solvents. Chem. Chem. Technol. 2015, 9, 1-4. https://doi.org/10.23939/chcht09.01.001
  13. Sergeev, V.V. Enthalpy of Mixing of Methacrylic Acid with Organic Solvents at 293 K. Russ. J. Phys. Chem. A. 2016, 90, 575- 578. https://doi.org/10.1134/S0036024416030274
  14. Sergeev, V.V. Enthalpies of Mixing of Butyl Methacrylate with Organic Solvents at 293 K. Russ. J. Phys. Chem. A, 2021, 95, 2177- 2180. https://doi.org/10.1134/s0036024421100228
  15. Spravochnik khimika, T 2; Nikolskii, B.P., Ed.; Khimiya: Leningrad, 1966.
  16. Svojstva organicheskikh soedinenii. Spravochnik; Potekhin, A.A., Ed.; Khimiya: Leningrad, 1984.
  17. Khimicheskii entsiklopedicheskii slovar; Knuyants, I.L., Ed.; Sov. Entsiklopediya: Moskva, 1983.
  18. Van Ness, H.C.; Abbott, M.M. Classical Thermodynamics of Nonelectrolyte Solutions; McGraw-Hill: New York, 1982.