Thermomechanical studies of polamide 6 compositions, modified with (MPM) montmorillonite-polyvinylpyrrolidone mixture, were performed. Polyamide 6 nanocomposites were obtained by the solution deposition. The influence of nanocomposite production conditions on morphological features of polymer blends were researched. Determination of thermomechanical properties makes it possible to define the optimal content of MPM in polyamide 6 blends.
1. Gavryliuk N.A., Prychodiko G.P., Kartel M.T. (2014). Oderzhannya ta vlastivosti nanokompozytiv na osnovi termoplastychnych polimeriv, napovnenych vuglecevymy nanotrubkamy. Poverchnost, 6(21), 206-240. http://www.irbis-nbuv.gov.ua/cgi-bin/irbis_nbuv
2. Suhyi K.M. (2013). Technologia oderzhannya nanokompozytiv na osnovi poliamidu I organomodyphikovanogo montmorylonitu. Voprosu himii i himichnych technologii, 5, 44-50. https://udhtu.edu.ua/public/userfiles/file/VHHT/2013/5/Sukhyy%202.pdf
3. Wang Z., Pinnavaia T.J. (1998). Nanolayer reinforcement of elastomeric polyurethane. Chem. Mater., 10, 7, 1820-1826. https://pubs.acs.org/doi/full/10.1021/cm980448n https://doi.org/10.1021/cm980448n
4. Garcia Lopez D., Gobernado-Mitrel., Fernandez J.F., Merino J.C., Pastor J.M. (2009). Properties of polyamide 6/clay nanocomposites processed by low cost bentonite and different organic modifiers. Polymer Bull., 62(6), 2493-2498. https://ur.booksc.me/book/7506240/3827f1 https://doi.org/10.1007/s00289-009-0051-1
5. Wang Z.; Pinnavaia T.J.(1998) Nanolayer Reinforcement of Elastomeric Polyurethane. Chem. Mater.,10 (12),3769-3771. https://pubs.acs.org/doi/full/10.1021/cm980448n https://doi.org/10.1021/cm980448n
6. Burnside S.D., Giannelis E.P. (1995). Synthesis and properties of new poly(dimethylsiloxane) nanocomposites. Chem. Mater., 7(9), 1597-1600. https://pubs.acs.org/doi/pdf/10.1021/cm00057a001 https://doi.org/10.1021/cm00057a001
7. Vaia R.A., Giannelis E.P.(1997).Polymer Melt Intercalation in Organically-Modified Layered Silicates: Model Predictions and Experiment. Macromolecules,30(25), 8000-8009. https://pubs.acs.org/doi/abs/10.1021/ma9603488 https://doi.org/10.1021/ma9603488
8. Chang K.-C., Chen S.-T., Lin H.-F., Lin C.-Y., Huang H.-H., Yeh J.-M., Yu Y.-H.(2008). The development of anthracene derivatives for organic light-emitting diodes. Eur. Polymer J.,44(1), 13-23. https://pubs.rsc.org/en/content/articlelanding/2012/JM/C2JM16855C https://doi.org/10.1016/j.orgel.2011.10.004
9. Jia Q., Zheng M., Shen R., Chen H.(2006). Effects of organophilic montmorillonite on hydrogen bonding, free volume and glass transition temperature of epoxy resin/polyurethane interpenetrating polymer networks. Chinese Sci. Bull,51(3),293-298. https://www.sciencedirect.com/science/article/abs/pii/S001430570600365X https://doi.org/10.1007/s11434-006-0293-3
10. V. Krasinskyi, O. Suberlyak, Y. Klym.(2016). Operational properties of nanocomposites based on polycaproamide and modified montmorillonite. Acta Mechanica Slovaca, 20(1), 52-55. https://www.actamechanica.sk/artkey/ams-201601-0008 https://doi.org/10.21496/ams.2016.008
11. V.V. Krasinskyi, O.V. Suberlyak, V.M. Zemke, M.V. Chekailo, M.O. Pankiv.(2021). Otrymannya nanokompozytiv na osnovi montmorylonitu ta poliamidu v rozchyni. Chemistry, technology and application of substances, Bulletin of the National University Lviv Polytechni, 4(1), 172-178.
https://doi.org/10.23939/ctas2021.01.172
12. D.О. Mishurov, V.L. Avramenko, О.О. Brovko.(2013). Nanokompozyty na osnovi polimeriv i sharuvatych sylikativ. Polimernyi zhurnal, 35(3), 217-230. http://gntb.gov.ua/files/vv/nanot13_2.pdf
13. О.V. Suberlyak, N.M. Baran, G.V. Yatsulchak. (2017). Phizyko-mechanichni vlastyvosti plivok na osnovi sumishej poliamidu z polivinilpirolidonom. Phizyko-himichna mechanika materialiv, 53(3), 93-97. http://www.irbis-nbuv.gov.ua/cgi-bin/irbis_nbuv/cgiirbis_64.
14.Krasinskyi V., Suberlyak O., Kochubei V., Jachowicz T., Dulebova L., Zemke V. (2020). Nanocomposites based on polyamide and montmorillonite obtained from a solution. Advances in Science and Technology Research Journal, 14(3), 192-198. http://www.astrj.com https://doi.org/10.12913/22998624/122297
15. ISO 306:2004. Plastics. Thermoplastic materials determination of Vicat softening temperature (VST), 1991, 8. https://docs.cntd.ru/document/1200110856
16. Krasinskyi V., Suberlyak O., Sikora J., Zemke V. (2021) Nanocomposites based on polyamide-6 and montmorillonite intercalated with polyvinylpyrrolidone [Electronic resource] .Polymer-Plastics Technology and Materials. https://www.tandfonline.com/doi/full/10.1080/25740881.2021.1924201 https://doi.org/10.1080/25740881.2021.1924201
17. Levytskyi V.Ye., Tarnavskyi A.B., Suberlyak O.V. (2004). Termomechanichni vlastyvosti sumishei poliamid-polivinilpirolidon.Chemistry, technology and application of substances, 497,141-143. https://ena.lpnu.ua/handle/ntb/12005
18. V.Levytskyi, A.Masyuk, D.Katruk, R.Kuziola, M.Bratychak jr., N.Chopyk, U.Khromyak. .(2020). Influence of polymer-silicate nucleator on the structure and properties of polyamide 6. Chemistry & Chemical Technology, 14(4),496-503. https://science2016.lp.edu.ua. https://doi.org/10.23939/chcht14.04.496