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  3. Volume 6, Number 1
  4. Influence of reaction conditions on the selectivity of the process of epoxidation of oct-1-ene by tert-butyl hydroperoxide in the presence of МоВ

Influence of reaction conditions on the selectivity of the process of epoxidation of oct-1-ene by tert-butyl hydroperoxide in the presence of МоВ

CTAS.
2023;
, Number 1
: 22-26
https://doi.org/10.23939/ctas2023.01.022
Authors:
  1. M.O. Zhukrovska
  2. Zoryana Komarenska
1
Lviv Polytechnic National University
2
Lviv Polytechnic National University

The influence of the reaction conditions on the selectivity of the interaction of oct-1-ene with tert-butyl hydroperoxide in the presence of MoB was investigated. It is shown that the selectivity of 1,2-epoxyoctane formation can vary depending on the reaction conditions.With the participation of the activated form of the catalyst, the selectivity increases significantly, but does not reach 100%. The optimal reaction conditions under which the selectivity of 1,2-epoxyoctane formation exceeds 90% have been established.

oxidation
epoxidation
selectivity
conversion
catalyst.
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