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  3. Volume 15, Number 3, 2021
  4. Voltammetric Determination of Pd(II) Using 5-Hydroxyimino-4-imino-1,3-thiazolidin-2-one after a Thermal Activation of the Interaction

Voltammetric Determination of Pd(II) Using 5-Hydroxyimino-4-imino-1,3-thiazolidin-2-one after a Thermal Activation of the Interaction

JCCT.
2021;
Volume 15, Number 3
: pp. 324 - 329
https://doi.org/10.23939/chcht15.03.324
Authors:
  1. Petro Rydchuk
  2. Oksana Labyk
  3. Lesya Oleksiv
  4. Oleksandr Tymoshuk
  5. Taras Chaban
1
Ivan Franko National University of Lviv
2
Central Research Laboratory and Laboratory of Industrial Toxicology, Danylo Halytsky Lviv National Medical University
3
Ivan Franko National University of Lviv
4
Ivan Franko National University of Lviv
5
Danylo Halytsky Lviv National Medical University

The interaction of Pd(II) with 5-hydroxyimino-4-imino-1,3-thiazolidin-2-one (HITO) was investigated over the pH range of 1.0–10.0. Optimal conditions for the voltammetric determination of Pd(II) were established. A new voltammetric method of Pd(II) determination by the peak of complex using NaCl as a supporting electrolyte at pH 2.0 was developed with the limit of detection 2.0∙10-7 M. The study of the method’s selectivity was presented in the work. The correctness of the method was confirmed by the analysis of model solutions and the real sample (resistor SP5-35B).

palladium
voltammetric determination
azolidone
oxime
thermal activation
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