voltammetric determination | Academic Journals and Conferences

Voltammetric Determination of Pd(II) Using 5-Hydroxyimino-4-imino-1,3-thiazolidin-2-one after a Thermal Activation of the Interaction

The interaction of Pd(II) with 5-hydroxyimino-4-imino-1,3-thiazolidin-2-one (HITO) was investigated over the pH range of 1.0–10.0. Optimal conditions for the voltammetric determination of Pd(II) were established. A new voltammetric method of Pd(II) determination by the peak of complex using NaCl as a supporting electrolyte at pH 2.0 was developed with the limit of detection 2.0∙10^-7 M. The study of the method’s selectivity was presented in the work.

Voltammetric Determination of Rhodium by Means of Furan-Oxime Derivatives in Industrial Samples with Considerable Content of Palladium

The selectivity of rhodium(III) voltammetric determination by means of furan-oxime derivatives has been investigated. The proposed methods have been approved on model solutions and during the determination of rhodium(III) in the presence of palladium(II) in complex industrial samples.

Voltammetric Determination of Iridium in Alloys Using Xylenol Orange

The possibility of iridium(IV) voltammetric determination using threephenylmethane dye (xylenol orange) has been investigated. The proposed technique has been tested using model solutions and in the process of iridium alloys analysis.