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  2. All Volumes and Issues
  3. Volume 17, Number 4, 2023
  4. Bamboo-Containing Composites with Environmentally Friendly Binders

Bamboo-Containing Composites with Environmentally Friendly Binders

JCCT.
2023;
Volume 17, Number 4
: pp. 807 - 819
https://doi.org/10.23939/chcht17.04.807
Authors:
  1. Omari Mukbaniani
  2. Tamara Tatrishvili
  3. Nikoloz Kvnikadze
  4. Tinatin Bukia
  5. Nana Pirtskheliani
  6. Tamar Makharadze
  7. Gia Petriashvili
1
1 Iv. Javakhishvili Tbilisi State University, 2 Institute of Macromolecular Chemistry and Polymeric Materials, Iv. Javakhishvili Tbilisi State University
2
Iv. Javakhishvili Tbilisi State University, 2 Institute of Macromolecular Chemistry and Polymeric Materials, Iv. Javakhishvili Tbilisi State University
3
Ivane Javakhishvili’ Tbilisi State University, Department of Macromolecular Chemistry; Institute of Macromolecular Chemistry and Polymeric Materials, Ivane Javakhishvili Tbilisi State University
4
Vladimir Chavchanidze Institute of Cybernetics of the Georgian Technical University
5
Institute of Macromolecular Chemistry and Polymeric Materials, Ivane Javakhishvili Tbilisi State University, Sokhumi State University, Faculty of Natural Sciences, Mathematics, Technologies and Pharmacy,
6
Ivane Javakhishvili Tbilisi State University R.Agladze Institute of Inorganic Chemistry and Electrochemistr
7
Vladimir Chavchanidze Institute of Cybernetics of the Georgian Technical University

The environmentally friendly binder - poly[(trimethoxy)4-vinylphenethyl)] silane was synthesized for the first time via Friedel-Crafts alkylation reaction, which was conducted by the reaction of polystyrene with vinyltrimethoxysilane in the presence of anhydrous AlCl3.The synthesized polymer was identified using 1H, 13C, 1H COSY NMR, and FTIR spectroscopy. Bamboo sawdust-based composites with various dispersion properties have been created using synthetic trimethoxysilylated polystyrene (TMSPSt) and styrenewith various degrees of silylation (5-10%). Composite materialsbased on bamboo powder with various organic/inorganic additives, flame retardants, and antioxidants, were processed at different temperatures and pressures using the hot pressing method. Obtained compositeswere studied by Fourier transformation infrared spectroscopy (FTIR), optical and scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDS). Thermal stability of the obtained materials was determined by thermogravimetry and the Vicat method. Also, water absorption and some mechanical properties were studied.

Friedel-Crafts reaction
silylated polystyrene
antipirene
bamboo powder
FTIR and NMR spectroscopy
mechanical properties
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