1. JCCT
  2. Всі випуски
  3. Випуск 17, Номер 4, 2023
  4. Бамбуковмісні композити з екологічно чистими в'яжучими речовинами

Бамбуковмісні композити з екологічно чистими в'яжучими речовинами

JCCT.
2023;
Випуск 17, Номер 4
: cc. 807 - 819
https://doi.org/10.23939/chcht17.04.807
Автори:
  1. Omari Mukbaniani
  2. Tamara Tatrishvili
  3. Nikoloz Kvnikadze
  4. Tinatin Bukia
  5. Nana Pirtskheliani
  6. Tamar Makharadze
  7. Gia Petriashvili
1
1 Iv. Javakhishvili Tbilisi State University, 2 Institute of Macromolecular Chemistry and Polymeric Materials, Iv. Javakhishvili Tbilisi State University
2
Iv. Javakhishvili Tbilisi State University, 2 Institute of Macromolecular Chemistry and Polymeric Materials, Iv. Javakhishvili Tbilisi State University
3
Ivane Javakhishvili’ Tbilisi State University, Department of Macromolecular Chemistry; Institute of Macromolecular Chemistry and Polymeric Materials, Ivane Javakhishvili Tbilisi State University
4
Vladimir Chavchanidze Institute of Cybernetics of the Georgian Technical University
5
Institute of Macromolecular Chemistry and Polymeric Materials, Ivane Javakhishvili Tbilisi State University, Sokhumi State University, Faculty of Natural Sciences, Mathematics, Technologies and Pharmacy,
6
Ivane Javakhishvili Tbilisi State University R.Agladze Institute of Inorganic Chemistry and Electrochemistr
7
Vladimir Chavchanidze Institute of Cybernetics of the Georgian Technical University

Уперше синтезовано екологічно чисту в'яжучу речовину– полі[(триметокси)4-вінілфенетил)]силан за допомогою реакції алкілування Фріделя-Крафтса, яку проводили взаємодією полістирену з вінілтриметоксисиланом у присутності безводного AlCl3. Синтезований полімер було ідентифіковано за допомогою 1H, 13C, 1H COSY ЯМР іFTIR спектроскопії. Композити на основі бамбукової тирси з різними дисперсійними властивостями були створені з використанням синтетичного триметоксисилільованогополістирену(TMSPSt) та стирену з різним ступенем силілювання (5-10%). Композиційні матеріали на основі бамбукового порошку з різними органічними/неорганічними добавками, антипіренамий антиоксидантами були оброблені за різних температур і тисків методом гарячого пресування. Отримані композити досліджували методами інфрачервоної спектроскопії з перетворенням Фур'є(FTIR), оптичної та растрової електронної мікроскопії (SEM), а також енергодисперсійної рентгенівської спектроскопії (EDS). Термостабільність отриманих матеріалів визначали за допомогою термогравіметрії та методу Віка. Також досліджено водопоглинання та деякі механічні властивості.

реакція Фріделя-Крафтса
силільований полістирен
антипірен
бамбуковий порошок
FTIR і ЯМР спектроскопія
механічні властивості
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