The Selective Ethylbenzene Oxidation by Dioxygen into -Phenyl Ethyl Hydroperoxide, Catalyzed with Triple Catalytic System {NiII(acac)2+NaSt(LiSt)+PhOH}. Formation of Nanostructures {NiII(acac)2•NaSt•(PhOH)}n with Assistance of Intermolecular H-Bonds

Ludmila Matienko, Vladimir Binyukov, Larisa Mosolova and Gennady Zaikov

The role of intra- and intermolecular H-bonds in mechanisms of catalysis with triple heterobinuclear hetero ligand complexes NiII(acac)2∙NaSt(LiSt)∙PhOH, including nickel and redox-inactive metal Na(Li), in the ethylbenzene oxidation by dioxygen into -phenyl ethyl hydroperoxide is discussed. The AFM method has been used for research of the stable supramolecular nanostructures formation possibility on the basis of triple complex NiII(acac)2∙NaSt∙PhOH, with the assistance of intermolecular H-bonds.

[1] Weissermel K. and Arpe H.-J.: Industrial Organic Chemistry, 3nd edn. Transl. by Lindley C. VCH., New York 1997.
[2] Matienko L.: Ch. 2 [in:] D’Amore A. and Zaikov G. (Eds.), Reactions and Properties of Monomers and Polymers. Nova Sience Publ. Inc., New York 2007.
[3] Matienko L., Mosolova, L. and Zaikov G.: Selective Catalytic Hydrocarbons Oxidation. New Perspectives. Nova Science Publ. Inc., New York 2010. 
[4] Matienko L. and Mosolova L.: Oxidation Commun., 2007, 30, 282.
[5] Dubey M., Koner R. and Ray M.: Inorg. Chem., 2009, 48, 9294. 
[6] Leninger St., Olenyuk B. and Stang P.: Chem. Rev., 2000, 100, 853.
[7] Stang P. and Olenyuk B.: Acc. Chem. Res., 1997, 30, 502. 
[8] Beletskaya I., Tyurin V., Tsivadze A. et al.: Chem. Rev., 2009, 109, 1659. 
[9] Matienko L., Binyukov V., Mosolova L. and Mil E.: J. Character. & Developmn. Novel Mat., 2011, 4, 12. 
[10] Fukuzumi S. and Ohkubo K.: Coord. Chem. Rev., 2010, 254, 372.
[11] Valentine J., Doucette P. and Potter S.: Annu. Rev. Biochem., 2005, 74, 63.
[12] Dani C. and Das A.: Indian J. Chem. Sect. A., 1984, 23, 1041.
[13] Aminabhovi T., Biradar N. and Divaka M.: Inorg. Chim. Acta, 1984, 92, 99.
[14] Park Y., Ziller J. and Borovik A.: J. Am. Chem. Soc., 2011, 133, 9258.