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  3. Volume 8, Number 3, 2014
  4. Synthesis of Heterometal Copolymer Complexes with Fragments of Mn(II) and Zn(II) -Diketonates

Synthesis of Heterometal Copolymer Complexes with Fragments of Mn(II) and Zn(II) -Diketonates

JCCT.
2014;
Volume 8, Number 3
Authors: 

Igor Voloshanovsky, Olga Shevchenko, Anastasiia Schastlyvets and Kateryna Burenkova

Heterometal polymer complexes with -diketonate fragments have been obtained via styrene triple copolymerization with polyfunctional components of radical polymerization – vinyl--diketonates of 5-methyl-5-hexene-2,4-ditionates Mn(II) and Zn(II). The process was carried out in a block and dimethylformamide solution in the presence and absence of additional initiator – benzoyl peroxide. Varying the chelated metals concentration, the presence of solvent and additional initiator one may control the concentration and metal ratio in the macromolecule, as well as products molecular weight.

radical copolymerization
vinyl--diketonate
inhibitor
heterometal complex

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