адсорбція

Kinetics of Low Molecular Substances Sorption by the Polymer Mixtures

The sorption capacity of polymer blends was analyzed on the basis of absorption kinetics. The study was carried out in an adsorption-active medium with different degrees of deformation. Heptane and butanol were used as adsorption-active media. The influence of the chemical nature of the adsorbate on the sorption process was studied. The free volume fractions for each sample of the composition were calculated. The ability of materials to absorb different amounts of substances allows us to identify the behavior peculiarities of the interfacial regions of different chemical compositions.

Adsorption Properties of Hydrophobic Porous Coordination Polymers of Zinc-Oxalic Acid with Triazole and Amino Triazole Mixture Ligands

The porous coordination polymers were prepared from Zn2+ and oxalic acid with 2 linker ligands, 1,2,4-triazole (Taz) and 3-amino-1,2,4-triazole (ATaz). The adsorption of N2 after adsorption of degassed CO2 in the pore frameworks increased by 3 times. The flexibility of this structure is due to the interaction of CO2 molecules with the amine groups contained in it, thereby increasing its porosity.

Magnetically Sensitive Carbon-Based Nanocomposites for the Removal of Dyes and Heavy Metals from Wastewater: A Review

The methods of wastewater treatment from heavy metal ions and dyes are analyzed, and the key advantages of powdered magnetically sensitive carbon nanocomposites as adsorbents are shown. Methods for selecting and preparing raw materials and activators for the synthesis of such nanocomposites are considered, and methods for synthesizing nanocomposites are analyzed. The properties, modeling of adsorption kinetics and isotherms, and efficiency of magnetic carbon nanocomposites for wastewater treatment from dyes and heavy metals are described.

DECARBONISATION OF INDUSTRIAL GAS EMISSIONS BY ADSORPTION METHODS

The article is dedicated to the problem of decarbonising industrial gas emissions using adsorption methods. The article examines promising approaches to reducing carbon dioxide (CO₂) emissions using adsorption materials with high selectivity and efficiency in capture processes. The purpose of the study is to determine the adsorption capacity of various types of adsorbents, including synthetic and natural materials, in particular, fly ash synthesised by the hydrothermal method, zeolite obtained by the sintering method, natural zeolite, and fly ash from thermal power plants.

Nonlinear Isotherm Adsorption Modelling for Copper Removal from Wastewater by Natural and Modified Clinoptilolite and Glauconite

The paper presents the results of the $Cu^{2+}$ adsorption on natural and thermally/microwave-treated clinoptilolite and glauconite. XPS experiments were performed. The relationship between the adsorbed matter and the equilibrium concentration in wastewater is described by four two-parameter isotherm models and four three-parameter adsorption isotherm models.

Adsorption of Zinc and Iron Ions from Aqueous Solution Using Waste Material as Adsorbent

Reducing or eliminating ions of toxic heavy elements such as iron and zinc from aqueous solutions has been adopted in this research. The batch process is used to remove metal ions using a cheap adsorbent material that is called hawthorn nucleus. In addition, the influences of contact time, pH, metal ions concentration, and adsorbent dose on the removal percentage have been studied.

Use of Chemically Modified Chitosan for the Adsorptive Removal of Toxic Metal Ions in Aqueous Solutions

Chemical modification of chitosan was successfully carried out using three derivatives namely: 3 hydroxybenzaldehyde, 2,3-dihydroxybenzaldehyde, and 3,5-di-tert-butyl-2-hydroxybenzaldehyde by a condensation reaction. Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), Brunauer–Emmett–Teller (BET) surface area, thermal gravimetric analysis (TGA), and X-ray diffraction (XRD) methods were performed for characterization of the chitosan-derived Schiff base adsorbent materials.

An Insightful Approach to Understanding the Mechanism of Amino Acid Adsorption on Inorganic Surfaces: Glycine on Silica

The adsorption of glycine on amorphous silica surface has been studied to demonstrate the catalytic activity of silica surfaces towards the formation of peptide bonds on prebiotic earth. Silica nanoparticles were synthesized using a microwave assisted method and the nanoparticles were characterized using SEM. Glycine was adsorbed from aqueous solution on the nanoparticles and the adsorption behavior was characterized using FTIR and TGA analyses. At a glycine concentration of 0.5M and at pH=7, favorable adsorption was observed which obeyed the Langmuir isotherm model.

Synthesis, Sorption Properties, and Evaluation of Silica Gel with Adsorbed Poly[8-Oxyquinoline Methacrylate] as a Sorbent for Cu(II), Cd(II), Pb(II) and Fe(III) Ions

In the present study, a novel functionalized silica composite was prepared by adsorption of poly[8- oxyquinoline methacrylate] on the surface of silica gel. Immobilization of poly[8- oxyquinoline methacrylate] on the silica gel surface was confirmed using IR spectroscopy and thermogravimetric analysis combined with mass spectrometry. Scanning electron microscopy revealed that the polymer almost completely covers the surface of the silica gel in the form of agglomerates of different geometric shapes.

STUDY OF THE PROCESS OF ADSORPTION OF PETROLEUM PRODUCTS METHODS OF MULTIVARIATE CLUSTER ANALYSIS

The article is devoted to studying the process of adsorption of oil products using multivariate cluster analysis methods. The study solves the problem of environmental pollution with petroleum substances and the search for effective cleaning methods. The work aims to study the prospects of using synthetic zeolites to effectively purify industrial wastewater from oil products.