Cross-linked nanocomposite hydrogels based on poly(acryl amide) and mineral nanoparticles (NP) of hydroxyapatite (HAP), ZnO, TiO2 modified by reactive polymers were synthesized via the technique of polymerization filling. It was shown that physico-mechanical properties of obtained nanocomposites are determined to a great extend by the nature of the modifier of mineral NP.
The problem of permanent and prolonged pollution of soils by various kinds of pollutants, in particular heavy metals, was analyzed. Experimental investigations of penetration of copper sulfate into a vertical soil profile have been carried out. The adsorption capacity of the sandy environment of copper sulfate
was experimentally determined.
The adsorption of Copper (II) and Chromium (III) from aqueous solution by natural zeolite was investigated in fixed bed column. The effects of selected operating parameters such as flow rate and bed depth were evaluated. The breakthrough data are fitted well to Bed Depth Service Time (BDST) and Thomas models with high correlation coefficient, R2 = 0,91. The results showed that zeolite can be an effective adsorbent for Copper (II) and Chromium (III) removal.
The adsorption method of after-treatment of wastewater from the production of vegetable oils was investigated. The reasons of choice the activated carbon as adsorbent was justified. The statics and the kinetics of the adsorption process by activated carbon the organic component from the wastewater of oil production after extraction cleaning was investigated. The experimental data based on the theory of Freundlich and Langmuir were processed and the main constants of the process were defined.
An optimized by hardware complexity method for measuring of positron annihilation lifetime spectra was proposed and used to investigation of humidity-sensitive MgO-Al2O3 ceramics with advanced nanoporosity. Positron-positronium annihilation spectrum were analyzed using four-component fitting procedures. It is shown that this technique can be used to investigation of nanopores transformation in humidity-sensitive MgO-Al2O3 ceramics as porosimetry method. It is shown that Tao-Eldrup model can be used for study of size of nanopores smaller then 1,5 nm.
This article describes the life and scientific priorities of professor Myroslav Malovanyy. It also provides details and results of a joint research with his students of a liquid media treatment from different types of pollution. The main research and its results are illustrated, as well as environmental technologies that were developed by using the archived results.
The aim of this work was to study the process of adsorption of Copper and Chromium cations by natural zeolites in static conditions. The change of the chemical composition of the surface of the zeolite as a result of sorption of heavy metals was investigated. The influence of the type of the ions and pH selectivity in absorption of heavy metals removal by zeolite was analysed. The reasons for the selective extraction of Copper from two-component solution were explained.
The adsorption properties of Transcarpathian clinoptilolite regarding Cr (VI) ions is studied. It was found that the adsorption isotherm has s-like form and belongs to the isotherm of type II. It is established that the adsorption proceeds further after the formation of monomolecular adsorption layer. It leads to the cteation of dimolecular layer. Вивчено адсорбційні властивості закарпатського клиноптилоліту стосовно іонів Cr (VI). З’ясовано, що ізотерма адсорбції має s-подібний вигляд і належить до ізотерми ІІ типу.
The different methods of water purification from bacteria of the genus Bacillus are observed. The comparative characteristics of these methods is made. Розглянуто різні методи очищення води від бактерій роду Bacillus. Зроблена порівняльна характеристика цих методів.
The problem of penetration of nitrogen fertilizers in the soil is analyzed. The influence of adsorption process on the rate of transfer of fertilizers in the vertical profile of the soil is determined. Experimental researches of adsorption properties of soil environment on the base of absorption of calcium nitrate by soil are done. Проаналізовано проблему проникнення азотних добрив вглиб ґрунту. Визначено вплив процесу адсорбції на швидкість перенесення добрив по вертикальному профілю ґрунту.