The article deals with the results of theoretical and experimental research on the production of ceramic pigments of blue color with the structure of spinel on the basis of slag of aluminothermal production of ferrotitanium. The sequence of the physical and chemical processes that determine the formation of the set of crystalline phases under drossy pigments burning was established. The influence of the concentration of cobalt oxide and the temperature of researched pigments firing on their optical-color characteristics was studied. The application of the developed pigments for glaze coatings painting was shown.
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