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  3. Volume 14, Number 2, 2020
  4. Ferrocenylmethylnucleobases Synthesis, DFT Calculations, Electrochemical and Spectroscopic Characterization

Ferrocenylmethylnucleobases Synthesis, DFT Calculations, Electrochemical and Spectroscopic Characterization

JCCT.
2020;
Volume 14, Number 2
: pp. 146 - 153
https://doi.org/10.23939/chcht14.02.146
Authors:
  1. Elhafnaoui Lanez
  2. Lazhar Bechki
  3. Touhami Lanez
1
1 University of El Oued, VTRS Laboratory 2 University of Ouargla, Chemistry Department
2
University of Ouargla, Chemistry Department
3
University of El Oued, VTRS Laboratory

Three ferrocenylmethylnucleobases (FcMeNb) were synthesized and characterized by cyclic voltammetry, electronic absorption, FT-IR and NMR spectroscopy. The energy of frontier molecular orbitals was determined using DFT/B3LYP method combined with 6-311++G(d,p) basis set in acetonitrile. The lower standard rate constant values of the FcMeNb compounds as compared to ferrocene indicated slower electron transfer kinetics.

nucleobases
ferrocene
cyclic voltammetry
UV-Vis spectroscopy
DFT
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