Epoxy Composites Filled with Natural Calcium Carbonate. 2. Epoxy Composites Obtained in the Presence of Monomethacrylic Derivative of Epidian-6 Epoxy Resin

2020;
: pp. 343 - 352
1
Lviv Polytechnic National University
2
Lviv Polytechnic National University
3
Lviv Polytechnic National University
4
Gdansk University of Technology
5
Department of Polymer Technology, Gdansk University of Technology

On the basis of Epidian-6 epoxy resin and methacrylic acid a monomethacrylic derivative of Epidian-6 with free epoxy and methacrylic groups (MMADER) has been synthesized. The structure of MMADER was confirmed by IR spectroscopy. The thermal stability of MMADER has been established. The cross-linking of unfilled epoxy-oligomeric mixtures and mixtures filled with CaCO3 has been studied in the presence of MMADER. By means of IR spectroscopy, the chemistry of the formation of mixtures based on Epidian-5, oligoesteracrylate TGM-3, MMADER and polyethylene polyamine has been established. Physico-mechanical characteristics of epoxy-oligomeric mixtures filled with CaCO3 have been established.

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