Синтез і дослідження властивостей геополімерних матеріалів, одержаних з використанням місцевої природної сировини та промислових відходів

2023;
: cc. 711 - 718
1
IvaneJavakhishvili Tbilisi State University, Alexander Tvalchrelidze Caucasian Institute of Mineral Resources
2
Ivane Javakhishvili Tbilisi State University, Raphael Agladze Institute of Inorganic Chemistry and Electrochemistr
3
Ivane Javakhishvili Tbilisi State University, Alexander Tvalchrelidze Caucasian Institute of Mineral Resources
4
Ivane Javakhishvili Tbilisi State University, Alexander Tvalchrelidze Caucasian Institute of Mineral Resources
5
Ivane Javakhishvili Tbilisi State University, Alexander Tvalchrelidze Caucasian Institute of Mineral Resources
6
Ivane Javakhishvili Tbilisi State University, Alexander Tvalchrelidze Caucasian Institute of Mineral Resources

Описано синтез геополімерних матеріалів з використанням термомодифікованих глинистих порід Грузії та металургійного гранульованого доменного шлаку, а також дослідження їхніх фізико-механічних властивостей, довговічності та корозійної стійкості в агресивних розчинах. Використано методи хімічного, рентгенофазового, диференційно-термічного аналізу та сканувальної електронної мікроскопії.

  1. Levytska, O.;Dolzhenkova, O.; Sichevyi, O.;Dorhanova, L. Masonry Unit Manufacturing Technology Using Polymeric Binder.Chem. Chem. Technol.2020, 14, 88–92.https://doi.org/10.23939/chcht14.01.088
  2. Savvova, O.; Voronov, H.; Fesenko, O.; Riabinin, S.; Tymofieiev, V. High-Strength Glass-Ceramic Material With Low Temperature Formation. Chem. Chem. Technol. 2022, 16, 337–344. https://doi.org/10.23939/chcht16.02.337
  3. Shapoval, S.; Shapoval, P; Zhelykh, V.; Pona, O.; Spodyniuk, N.; Gulai, B.; Savchenko, O.; Myroniuk, K. Ecological and Energy Aspects of Using the Combined Solar Collectors for Low-Energy Houses. Chem. Chem. Technol. 2017, 11, 503–508. https://doi.org/10.23939/chcht11.04.503
  4. Avaliani, M.; Chagelishvili, V.; Shapakidze, E.; Gvelesiani, M.; Barnovi, N.; Kveselava, V.; Esakia, N. Crystallization Fields of Condensed Scandium and Silver Phosphates and Regularities of Their Formation. European Chemical Bulletin2019, 8, 164–170.
  5. Purbasari, A.; Ariyanti, D.; Sumardiono, S.; Khairunnisa, K.; Sidharta, T. Adsorption Kinetics and Isotherms of Cu(II) and Fe(II) Ions from Aqueous Solutions by Fly Ash-Based Geopolymer. Chem. Chem. Technol.2022, 16, 169–176. https://doi.org/10.23939/chcht16.02.169
  6. Glukhovsky, V.D. Soil Silicates;Gosstroyizdat: Kiev,1959.
  7. Glukhovsky, V.D.;Krivenko, P.V.;Ryumina, P.V.;Gerasimchuk, V.L. Production of Concrete and Structures Based on Slag-Alkali Binders;Budivelnik: Kiev, 1988.
  8. Krivenko, P. Alkaline Cements. In Proceedings of the First International Conference on Alkaline Cements and Concrete; VIPOL Stock Company: Kiev, 1994;pp 11–129.
  9. Krivenko, P.V. Special Alkaline Cements;Budivelnyk: Kiev,1995.
  10. Krivenko, P. Review. Why Alkaline Activation – 60 Years of the Theory and Practice of Alkali-Activated Materials. J. Ceram. Sci.Technol. 2017,08, 323–334. https://doi.org/10.4416/JCST2017-00042
  11. Davidovits, J. Soft Mineralurgy and Geopolymers. InProc. of Geopolymer 88 – Conference Internationale, Université de Technologie;Compiègne, France,1988; pp 49–56.
  12. Davidovits, J. Carbon-Dioxide Greenhouse-Warming: What Future for Portland Cement. In Proceedings, Emerging Technologies Symposium on Cement and Concretes in the Global Environment; Portland Cement Association: Chicago, Illinois, 1993; pp1–21.
  13. Duxon,P.;Fernández-Jiménez, A.; Provis, J.L.; Lukey, G.C.; Palomo A.; van Deventer, J.S.J. GeopolymerTechnology: The Current State of the Art. J. Mater. Sci.2007, 42, 2917–2933.https://doi.org/10.1007/s10853-006-0637-z
  14. Palomo, A.;Grutzeck, M.W.;Blanco, M.T. Alkali-Activated fly Ash Cement for Future. CemConcr Res1999,29,1323–1329.https://doi.org/10.1016/S0008-8846(98)00243-9
  15. Palomo, A.; Krivenko, P.; Garcia-Lodeiro, I.; Kavalerova, E.; Maltseva, O.; Fernández-Jiménez, A. A Review on Alkaline Activation: New Analytical Perspectives.Mater. deConstruccion2014, 64, 022.
  16. Shapakidze, E.; Nadirashvili, M.; Maisuradze, V.; Gejadze, I.; Avaliani, M.; Todradze, G. Elaboration of Optimal Mode for Heat Treatment of Shales for Obtaining Metakaolin. European Chemical Bulletin2019,8, 31–33.
  17. Shapakidze, E.; Avaliani, M.; Nadirashvili, M.; Maisuradze, V.; Gejadze, I.; Petriashvili, T. Obtaining of Geopolymer Binders Based on Thermally Modified Clay Rocks of Georgia. Nano Studies2020, 20, 43–52. http://dx.doi.org/10.13140/RG.2.2.18756.17281
  18. Shapakidze, E.; Avaliani, M.; Nadirashvili, M.; Maisuradze, V.; Gejadze, I.; Petriashvili, T.GeopolymersBased on Local Rocks as a Future Alternative to Portland Cement. In Advanced Materials, Polymers, and Composites: New Research on Properties, Techniques, and Applications; Apple Acad. Press: USA, 2020, 3;pp 351–358. http://dx.doi.org/10.13140/RG.2.2.28081.12644
  19. Fernando, P.T.; Said, J. Retraction Note: Resistance to Acid Attack, Abrasion and Leaching Behavior of Alkali-Activated Mine Waste Binders.Mater Struct2021, 54,154.https://doi.org/10.1617/s11527-021-01738-2
  20. Bakharev, T. Resistance of Geopolymer Materials to Acid Attack. CemConcr Res2005, 35, 658–670.https://doi.org/10.1016/j.cemconres.2004.06.005
  21. Hewlett, P.C. Lea’s Chemistry of Cement Concrete, third ed.; John Wily and Sons, Inc.: New York, 1998.
  22. Palomo, A.; Blanco-Varela, M.T.; Granizo, M.L.; Puertas, F.; Vazquez, T.;Grutzeck, M.W. Chemical Stability of Cementitious Materials Based on Metakaolin. CemConcr Res1999,29, 997–1004.https://doi.org/10.1016/S0008-8846(99)00074-5
  23. Shaikh, F.U.A. Effects of Alkali Solutions on Corrosion Durability of Geopolymer Concrete.Adv. Cem. Res. 2014, 2(2).109–123.https://doi.org/10.12989/acc.2014.2.2.109
  24. Bankharev, T. Durability of Geopolymer Materials in Sodium and Magnesium Sulfate Solutions. CemConcr Res2005,35, 1233–1246.https://doi.org/10.1016/j.cemconres.2004.09.002
  25. Kim, Y.Y.; Lee, B.J.; Saraswathy, V.; Kwon, S.J. Strength and Durability Performance of Alkali-Activated Rice Husk Ash Geopolymer Mortar. Sci. World. J. 2014,2014,209584.https://doi.org/10.1155/2014/209584
  26. Lingyu, T.; Dongpo, H.; Jianing, Zh.;Hongguang, W. Durability of Geopolymersand Geopolymer Concretes: A Review. Rev. Adv. Mater. Sci. 2021,60, 1–14. https://doi.org/10.1515/rams-2021-0002