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  3. Volume 4, Number 1
  4. Acrylic plant oil-based monomers with high content of oleic acid esters

Acrylic plant oil-based monomers with high content of oleic acid esters

CTAS.
2021;
Volume 4, Number 1
: 230-236
https://doi.org/10.23939/ctas2021.01.230
Authors:
  1. V. F. Kirianchuk
  2. Z. I. Demchuk
  3. Ananiy Kohut
  4. Stanislav Voronov
  5. A. Voronov
1
Lviv Polytechnic National University
2
Lviv Polytechnic National University
3
Lviv Polytechnic National University
4
Lviv Polytechnic National University
5
North Dakota State University

New acrylic monomers were obtained via transesterification of olive, canola, and high-oleic soybean oils by N-hydroxyethylacrylamide. The kinetic features of homopolymerization of these monomers were studied and the influence of linoleic (C18: 2) and linolenic (C18: 3) acid esters on the polymerization rate and the molecular weight of homopolymers were compared. It was found that the chain transfer and propagation rate constants increase in monomer’s range: olive (CM = 0.016) <high-oleic soybean (CM = 0.018) <canola (CM = 0.025). Features of homopolymerization are associated with varying degrees of unsaturation of fatty acid fragments.

canola oil
olive oil
high-oleic soybean oil
transesterification
plant oil-beased monomers
free radical polymerization

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