Application of Glutaraldehyde-Crosslinked Chitosan Membranes from Shrimp Shellwaste on Production of Biodiesel from Calophyllum Inophyllum Oil

: pp. 65 – 70
Siti Wafiroh, Murobbiyatul Wathoniyyah, Abdulloh Abdulloh, Yanuardi Rahardjo and Mochamad Zakki Fahmi

Airlangga University, Faculty of Science and Technology, Department of Chemistry, Surabaya 60115, Indonesia;;

The purification of biodiesel was performed using glutaraldehyde-crosslinked chitosan membrane to improve the quality and to reduce the cost of biodiesel production. Biodiesel was obtained by acid-based catalyzed transesterification of Calophyllum inophyllum oil. The results of this experiment showed that the amount of glycerol in biodiesel before the process is 0.3014±0.05 %. After the purification process performed for 1 h, the glycerol content in biodiesel has been reduced to 0.1429±0.09 %.

[1] Singh R. Hybrid Membrane Systems for Water Purification: Technology, Systems Design and Operations. Elsevier, 2006.
[2] Wafiroh S. and Humairo A: Proceed. 3rd Int. Conf. and Workshops on Basic and Applied Universitas Airlangga, Indonesia, Surabaya 2011, 324.
[3] Van Reis R. and Zydney A.: Curr. Opin. Biotechnol. 2001, 12(2), 208.
[4] Mittelbach M.: Bioresour. Technol., 1996, 56, 7.
[5] Neher A., Haas T., Arntz D. et al.: US Pat. 5387720A, Publ. Feb. 7, 1995.
[6] Wafiroh S. and Febriana H.: Proceed. 2nd Int. Conf. on Chemical Sciences, Indonesia, Yogyakarta 2010, 145.
[7] Pabby A., Rizvi S. and Requena A.: Handbook of Membrane Separations: Chemical, Pharmaceutical, Food, and Biotechnological Applications. CRC Press Taylor & Francis Group: Boca raton 2015.
[8] Dube M., Tremblay A. and Liu J.: Bioresour. Technol., 2007, 98, 639.
[9] Wang Y., Wang X., Liu Y. et al.: Fuel Process. Technol., 2009, 90, 422.
[10] Chaudhary J., Vadodariya N., Nataraj S. and Meena R.: ACS Appl. Mater. Interfaces, 2015, 7, 24957.
[11] Croisier F. and Jerome C.: Eur. Polym. J., 2013, 49, 780.
[12] Dotto G., Moura J., Cadaval T. and Pinto L.: Chem. Eng. J., 2013, 214, 8.
[13] Estevinho B., Rocha F., Santos L. and Alves A.: Trends Food Sci. Technol., 2013, 31, 138.
[14] Ikinci G., Senel S., Akincibay H. et al.: Int. J. Pharm., 2002, 235, 121.
[15] Saleh J., Tremblay A. and Dube M.: Fuel, 2010, 89, 2260.
[16] Berchmans H. and Hirata S.: Bioresour. Technol., 2008, 99, 1716.
[17] Kim S.-K.: Chitin, Chitosan, Oligosaccharides and Their Derivatives: Biological Activities and Applications. CRC Press Taylor & Francis Group, Boca raton 2010.
[18] Corazzari I.,; Nistico R., Turci F. et al.: Polym. Degrad. Stab., 2015, 112, 1.
[19] Khor E. and Lim L.: Biomaterials, 2003, 24, 2339.
[20] Mulder J.: Basic Principles of Membrane Technology. Springer Science & Business Media, London 2012.
[21] American Society for Testing and Materials (ASTM). "ASTM D6751-09, Standard Specification for Biodiesel Fuel Blend Stock (B100) for Middle Distillate Fuels." West Conshohocken, PA: ASTM, 2009.