1. JCCT
  2. All Volumes and Issues
  3. Volume 15, Number 4, 2021
  4. Synthesis of Antibacterially ActiveSilver Nanoparticles by Galvanic Replacement on Magnesium in Solutions of Sodium Polyacrylate in an Ultrasound

Synthesis of Antibacterially ActiveSilver Nanoparticles by Galvanic Replacement on Magnesium in Solutions of Sodium Polyacrylate in an Ultrasound

JCCT.
2021;
Volume 15, Number 4
: pp. 493–499
https://doi.org/10.23939/chcht15.04.493
Authors:
  1. Galyna Zozulya
  2. Orest Kuntyi
  3. Roman Mnykh
  4. Martyn Sozanskyi
1
Lviv Polytechnic National University
2
Lviv Polytechnic National University
3
Lviv Polytechnic National University
4
Lviv Polytechnic National University

“Green” synthesis of silver nanoparticles (AgNPs) by a galvanic replacement (GR) on magnesium in solutions of sodium polyacrylate (NaPA) under ultrasound (42 kHz) is reported. The mechanism of combined action of GR and ultrasound on the formation of nanoparticles is proposed. Synthesized solutions of AgNPs are characterized by an absorption maximum at 410 nm, the value of which does not depend on the concentrations of precursors (AgNO3 and NaPA) and the duration of the process. The dimensions of nanoparticles that have a spherical shape do not exceed 30 nm. With increasing concentration of surfactant, there is a tendency to decrease in size. The rate of synthesis of AgNPs increases almost in proportion to the concentration of AgNO3 in the solution, while the effect of NaPA concentration is negligible. The synthesized nanoparticles efficiently demonstrated a bactericide effect on Escherichia coli and Staphylococcus aureus.

silver nanoparticles
ultrasound
galvanic replacement
magnesium
sodium polyacrylate
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