Obtaining and Use of Coumarone-Indene-Carbazole Resin as a Modifier of Road Petroleum Bitumen. 2. Setting the Type and Amount of Catalyst

2023;
: pp. 450 - 459
1
Lviv Polytechnic National University
2
Lviv Polytechnic National University
3
Lviv Polytechnic National University
4
Lviv Polytechnic National University
5
Lviv Polytechnic National University
6
Lviv Polytechnic National University

In the presence of various catalysts (TiCl4, AlCl3, H2SO4), the process of obtaining a coumarone-indene-carbazole resin (CICR), which is produced from liquid products of coal coking, and its subsequent use for bitumen modification was investigated. The influence of the catalyst type on the yield and modifying properties of CICR (change in thermoplastic and adhesive properties of bitumen after adding the obtained resins to them) was studied. The effect of catalyst amount on the resin synthesis and subsequent modification of bitumen with the synthesized product was determined. According to the results, the optimal type and amount of the catalyst for obtaining CICR were chosen. The de-termined optimal amount of coumarone-indene-carbazole resin synthesized using the selected type of catalyst was found to have the most positive effect on the adhesive characteristics of road bitumen

  1. Modified Bitumen Market by Modifier Type https://www.marketsandmarkets.com/Market-Reports/modified-bitumen-market... (accessed 2017-01-01).
  2. Polymer modified bitumen market size https://www.fortunebusinessinsights.com/polymer-modified-bitumen-market-... (accessed 2022-02-01).
  3. Modified bitumen market https://www.mordorintelligence.com/industry-reports/modified-bitumen-market (accessed 2021-01-01).
  4. European asphalt pavement association http://www.eapa.org. (accessed 2021-03-15).
  5. Halkin, A.V.; Pyrih, Ya. I. Ohliad bitumnykh viazhuchykh, shcho vykorystovuiutsia v Ukraini. Dorohy i mosty 2021, 23, 60-75.
  6. Pershyi milion: rynok bitumu z pochatku roku zris na tretynu https://enkorr.ua/uk/news/pervyy_million_rynok_bituma_s_nachala_goda_vyr... (accessed 2021-10-22).
  7. Na piku: v serpni Ukraina importuvala 150 tys. t bitumiv https://enkorr.ua/uk/news/na_pike_v_avguste_ukraina_importirovala_150_ty... (accessed 2021-03-09).
  8. Ukravtodor. Derzhavne ahentstvo avtomobilnykh dorih Ukrainy https://ukravtodor.gov.ua/4489/povidomlennia_pro_opryliudnennia/60100.html (accessed 2020-01-12).
  9. Styrene-Butadiene-Styrene (SBS) Block Copolymer - Global Market Trajectory & Analytics https://www.researchandmarkets.com/reports/1824142/styrenebutadienestyre... (accessed 2022-10-07).
  10. Prysiazhnyi, Yu.; Borbeyiyong, G.I.; Pyshyev, S. Preparation and Application of Coumarone-Indene-Carbazole Resin as a Mod-ifier of Road Petroleum Bitumen. 1. Influence of Carbazole:Raw Materials Ratio. Chem. Chem. Technol. 2022, 16, 284-294. https://doi.org/10.23939/chcht16.02.284
  11. Litvinenko, M.S. Himicheskie produkty koksovania dlia proizvodstva polimernyh materialov; Metalurgizdat: Harkov, 1962.
  12. Zhang, J. X. Review of Coal Tar Preparation and Processing Technology. Adv. Mater. Res. 2012, 619, 286-289. https://doi.org/10.4028/www.scientific.net/AMR.619.286
  13. Сarbazole. Security passport https://www.carlroth.com/medias/SDB-9752-RU-RU.pdf?context=bWFzdGVyfHNlY... (accessed 2020-01-07).
  14. Rossi, C.O.; Teltayev, B.; Angelico, R. Adhesion Promoters in Bituminous Road Materials: A Review. App. Sci. 2017, 7, 524-534. https://doi.org/10.3390/app7050524
  15. Pyshyev, S.; Gunka, V.; Grytsenko, Y.; Bratychak, M. Poly-mer Modified Bitumen: Review. Chem. Chem. Technol. 2016, 10, 631-636. https://doi.org/10.23939/chcht10.04si.631
  16. Pyshyev, S.; Prysiazhnyi, Yu.; Sidun, Iu.; Shved, M.; Bor-beyiyong, G.I.; Korsh, D. Obtaining of Resins Based on Model Mixtures with Indene, Coumarone, and Styrene, and their Usage as Bitumen Modifiers. Pet. Coal 2020, 62, 341-346.
  17. Pyshyev, S.; Grytsenko, Yu.; Solodkyy, S.; Sidun, Iu.; Vollis, O. Using Bitumen Emulsions Based on Oxidated, Distillation and Modified Oxidated Bitumens for Slurry Seal Production. Chem. Chem. Technol. 2015, 9, 359-366. https://doi.org/10.23939/chcht09.03.359.
  18. Bratychak, M.; Gunka, V.; Prysiazhnyi, Yu.; Hrynchuk, Yu.; Sidun, Iu.; Demchuk, Yu.; Shyshchak, O. Production of Bitumen Modified with Low-Molecular Organic Compounds from Petroleum Residues. 1. Effect of Solvent Nature on the Properties of Petroleum Residues Modified with Formaldehyde. Chem. Chem. Technol. 2021, 15, 274-283. https://doi.org/10.23939/chcht15.02.274.
  19. DSTU EN 1426:2018 http://online.budstandart.com/ua/catalog/doc-page?id_doc=78299 (accessed 2019-06-01).
  20. DSTU EN 1427:2018 http://online.budstandart.com/ua/catalog/doc-page.html?id_doc=78301 (accessed 2019-06-01).
  21. DSTU 8825:2019 http://online.budstandart.com/ua/catalog/doc-page.html?id_doc=82135 (accessed 2020-01-01).
  22. DSTUBV.2.7-81-98 http://online.budstandart.com/ua/catalog/doc-page?id_doc=4804 (accessed 1999-03-01).
  23. DSTU 8787:2018 http://online.budstandart.com/ua/catalog/doc-page?id_doc=77885 (accessed 2019-06-01).
  24. Neiser, J., Gottweis, J. Indene, its polymers and copolymers; SPN, 1969.
  25. Gunka, V.; Prysiazhnyi, Yu.; Hrynchuk, Yu.; Sidun, Iu.; Demchuk, Yu.; Shyshchak, O.; Bratychak, M. Production of Bitu-men Modified with Low-Molecular Organic Compounds from Petroleum Residues. 2. Bitumen Modified with Maleic Anhydride. Chem. Chem. Technol. 2021, 15, 443-449. https://doi.org/10.23939/chcht15.03.443
  26. Mildenberg, R.; Zander, M.; Collin, G. Hydrocarbon Resins; Weinheim, New-York, Basel, Cambridge, Tokyo, VCH, 1997. https://doi.org/10.1002/9783527614653
  27. Koliandr, L.Ia.; Andreeva, V.S.; Kovaleva, N.Y.; Tolmachev, N.V.; Tolochko, A.A. Ob orhanyzatsyy proyzvodstva ynden-kumaronovykh smol metodom. Koks y khymyia 1984, 6, 29-34.
  28. Koliandr, L.Ia.; Andreeva, V.S.; Kovaleva, N.Y. Yssledo-vanye protsessa poluchenyia termoplastychnykh smol yz koksok-hymycheskoho syria metodom radykalnoi polymeryzatsyy. Khymy-cheskaia tekhnolohyia 1982, 3, 14-17.
  29. Amirova, L.; Andrianova, K.; Amirova, L. Processing me-thod, properties and application of functionally graded polymer materials based on the mixtures of poorly compatible epoxy resins. Polym. Polym. Compos. 2021, 29, 611-621. https://doi:10.1177/09673911211014763
  30. Pyshiev, S.V.; Hrytsenko, Yu.B.; Khlibyshyn, Yu.Ia.; Strap, H.M.; Koval, T.M. Vplyv pryrody polimeru na vlastyvosti modyfikovanykh bitumiv. East.-Eur. J. Enterp. Technol. 2014, 2, 4-8.
  31. Pyshiev, S.V.; Hrytsenko, Yu.B.; Nykulyshyn, I.Ie.; Hnativ, Z.Ia. Oderzhannia inden-kumaronovykh smol dlia modyfikatsii naftovykh dorozhnikh bitumiv. UhleKhymycheskyi zhurnal 2014, 5, 41-48.
  32. Pyshyev, S.; Grytsenko, Yu.; Bilushchak, H.; Pyshyeva, R.; Danyliv, N. Production of Indene-coumarone Resins as Bitumen Modifiers. Pet. Coal 2015, 57, 303-304.
  33. Gunka, V.; Prysiazhnyi, Yu.; Hrynchuk, Yu.; Sidun, Iu.; Demchuk, Yu.; Shyshchak, O.; Bratychak, M. Production of Bitu-men Modified with Low-Molecular Organic Compounds from Petroleum Residues. 2. Bitumen Modified with Maleic Anhydride. Chem. Chem. Technol. 2021, 15, 443-449. https://doi.org/10.23939/chcht15.03.443
  34. Pysh'yev, S.; Gunka, V.; Astakhova, O.; Prysiazhnyi, Ju.; Bratychak, M. Effect of Coal Quality on Its Desulphurization. Influence of the Organic Matter. Chem. Chem. Technol. 2012, 6, 443-450. https://doi.org/10.23939/chcht06.04.443