1. JCCT
  2. All Volumes and Issues
  3. Volume 17, Number 4, 2023
  4. Spontaneous Polymerization of 4-Vinylpyridine Monomer on Micron-Sized Mica Platelets

Spontaneous Polymerization of 4-Vinylpyridine Monomer on Micron-Sized Mica Platelets

JCCT.
2023;
Volume 17, Number 4
: pp. 800 - 806
https://doi.org/10.23939/chcht17.04.800
Authors:
  1. Fayçal Dergal
  2. Djahida Lerari
  3. Khaldoun Bachari
1
Centre de Recherche Scientifique et Technique en Analyses Physico-Chimiques, Laboratoire de Catalyse et Synthèse en Chimie Organique, Faculté des Sciences, Université de Tlemcen
2
Centre de Recherche Scientifique et Technique en Analyses Physico-Chimiques
3
Centre de Recherche Scientifique et Technique en Analyses Physico-Chimiques

In this study, we reported the spontaneous polymerization of two composite materials based on P4VP and mica at two different ratios, 4VP/mica/R=5 and 4VP/mica/R=10, noted as P4VP5@mica and P4VP10@mica, respectively. The obtained composites were characterized using thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). The polymerized P4VP on the inorganic surface has potential interest for the modification of the interfacial properties of the mica.

mica
4-vinylpyridine (4VP)
spontaneous polymerization
composite
  1. Ghannam, L.;Bacou, M.;Garay, H.; Shanahan, M.E.R.; François, J.; Billon, L. Elastomer Monolayers Adsorbed on Mica Surfaces by Nitroxide-Mediated Polymerisation. Polymer2004, 45, 7035-7045. https://doi.org/10.1016/j.polymer.2004.08.002
  2. Bacquet, M.; Martel, B.;Morcellet, M.; Benabadji, K.I.;Medjahed, K.;Mansri, A.;Meniai, A.H.;Lehocine, M.B. Adsorption of Poly (4-Vinylpyridine) onto Bentonites. Mater. Lett. 2004, 58, 455-459. https://doi.org/10.1016/S0167-577X(03)00524-X.
  3. Gan, D.; Lu, S.; Song, C.; Wang, Z. Physical Properties of Poly (Ether Ketone Ketone)/Mica Composites: Effect of Filler Content. Mater.Lett.2001, 48, 299-302. https://doi.org/10.1016/S0167-577X(00)00318-9
  4. Brotherson, B.; Deng, Y. Site Blocking Effect on the Conformation of Adsorbed Cationic Polyacrylamide on a Solid Surface. J. Colloid Interface Sci. 2008, 326, 324-328. https://doi.org/10.1016/j.jcis.2008.06.035
  5. Mansri, A.; Benabadji, K.I.;Desbrières, J.; François, J. Chromium Removal Using Modified Poly (4-Vinylpyridinium) Bentonite Salts. Desalination2009, 245, 95-107.https://doi.org/10.1016/j.desal.2008.06.012
  6. Brinks, M.K.;Studer, A. Polymer Brushes by Nitroxide-Mediated Polymerization. Macromol.Rapid Commun.2009, 30, 1043-1057. https://doi.org/10.1002/marc.200800720
  7. Parvole, J.; Billon, L.; Montfort, J.P. Formation of Polyacrylate Brushes on Silica Surfaces. Polym. Int.2002, 51, 1111-1116. https://doi.org/10.1002/pi.1045
  8. Escocio, V.;Altstadt, V.;Visconte, L.; de Carvalho, M.;Nunes, R. TPU/Mica Composites Prepared in Torque Rheometer: Processability, Mechanical Properties and Morphology.Chem. Chem. Technol.2011, 5, 191–195. https://doi.org/10.23939/chcht05.02.191
  9. Jumadilov, T.;Kondaurov, R.;Imangazy, A.;Myrzakhmetova, N.;Saparbekova, I. Phenomenon of Remote Interaction and Sorption Ability of Rare Cross-linked Hydrogels of Polymethacrylic Acid and Poly-4-vinylpyridine in Relation to Erbium Ions. Chem. Chem. Technol.2019, 13, 451-458. https://doi.org/10.23939/chcht13.04.451
  10. Marques, M.;Rosa, J.; Cruz, K. Influence of Chemical Treatment on Sodium Clay for Obtaining Polypropylene Nanocomposites.Chem. Chem. Technol.2011, 5, 433-438. https://doi.org/10.23939/chcht05.04.433
  11. Parvole, J.;Laruelle, G.;Guimon, C.; Francois, J.; Billon, L. Initiator‐Grafted Silica Particles for Controlled Free Radical Polymerization: Influence of the Initiator Structure on the Grafting Density.Macromol.Rapid Commun.2003, 24, 1074-1078. https://doi.org/10.1002/marc.200300035
  12. Kickelbick, G. Concepts for the Incorporation of Inorganic Building Blocks into Organic Polymers on a Nanoscale. Prog.Polym. Sci. 2003, 28, 83-114. https://doi.org/10.1016/S0079-6700(02)00019-9
  13. Mansri, A.;Ramdani, N. In situPolymerization of 4-Vinylpyridine/Bentonite Composites and their Application for Toluene Removal.Res. Chem.Intermed.2015, 41, 1765-1776.https://doi.org/10.1007/s11164-013-1310-1
  14. Mansri, A.;Dergal, F.; Billon, L. Formulation and Characterization of New pH Dependent [Alizarin‐poly (4‐vinylpyridine)‐mica] Pigments. Macromol. Symp.2015, 354, 131-144. https://doi.org/10.1002/masy.201400004
  15. Choukchou-Braham, E.;Benabadji, I.;Mansri, A.; François, J. Molecular Weight Influence on Viscosimetric Parameters of Poly (4-Vinylpyridine) Polymers. Eur. Polym. J. 2003, 39, 297-303. https://doi.org/10.1016/S0014-3057(02)00221-5.
  16. Mansri, A.; Frère, Y.;Chovino, C.;Gramain, P. Synthesis and Thermal Properties of Poly [n-(Monomethoxypolyethylene Oxide) - 4- Vinylpyridinium Salt]s. Des. Monomers Polym. 2000, 3, 55-66.https://doi.org/10.1163/156855500750198726
  17. Ghannam, L.;Parvole, J.;Laruelle, G.; Francois, J.; Billon, L. Surface‐Initiated Nitroxide‐Mediated Polymerization: A Tool for Hybrid Inorganic/Organic Nanocomposites ‘in situ’Synthesis. Polym. Int.2006, 55, 1199-1207.https://doi.org/10.1002/pi.1985