The structure of CuCl2, CuCl catalyst active centres on the surface of γ-Al2O3 has been investigated on the basis of X-ray diffraction analysis. The influence of the catalyst structure on the mechanism of ethylene oxidative chlorination has been determined. Using mass spectroscopy the difference in the structure of active centers and the mechanism of the deposited and impregnated types of CuCl2, CuCl/γ-Al2O3 catalysts in the process of ethylene oxidative chlorination into 1,2-dichlorethane has been studied.
[1] Kurta S.: Khіmіya і Tehnologіya Chlororganіchnyh Spoluk. Plai, Іvano-Frankіvsk 2009.
[2] Flid M. and Treger Yu.: Vinilchlorid. Himiya i Tehnologiya. V.1. Kalvis, Moskwa 2008.
[3] Flid M.: DSc thesis, FGUP NII “Sintez”, Russia, Mockwa 2002.
[4] Zolotovskii B.: DSc thesis, Novosibirsk, Rissia 1992.
[5] Kurta S., Haber M. and Mikitin І.: Khіm. Prom. Ukrainy, 2003, 55, 9.
[6] Kurta S., Mikitin І. and Pronik O.: Pat. Ukrainy 24933. Publ. July 25, 2007.
[7] Kurta S., Mikitin I., Haber M. and Skakun P.: Pat. Ukrainy 88262. Publ. June 25, 2009.
[8] Mikitin І.: PhD thesis, Lviv, Ukraine 2009.
[9] Kurta S., Mikitin I. and Kurta O.: Fіzika і Khіmіya Tverdogo Tіla, 2008, 9, 577.
[10] Kulik T., Barvinchenko V., Palyanica B. et al.: Zh. Fizicheskoi Khimii, 2007, 81, 88.
[11] Kurta S., Mikitin І. and Kurta O.: Fіzika і Khіmіya Tverdogo Tіla, 2008, 9, 143.
[12] Lamberti C., Prestipino C., Capello L. et al.: Int. J. Mol. Sci., 2001, 2, 230.
[13] Jorgensen C.: Progr. Inorg. Chem., 1979, 12, 101.
[14] Garilli M., Fatutto P. and Piga F.: La Chimica e l’Industria, 1998, 80, 333.
[15] Leofanti G., Padovan M., Garilli M. et al.: Int. J. Mol. Sci., 2001, 2, 244.
[16] Leofanti G., Marsella A., Cremaschi B. et al.: J. Catal., 2001, 202, 279.
[17] Kurta S., Mykytyn I. and Haber M.:Zh. Prikladnoi Khimii, 2005, 76, 1110.