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  4. Study of the Influence of Substituent R Nature in Phenylsulfones Derivatives PhSO2R on the Chemical Shifts of Phenyl Ring Protons in NMR 1H Spectra

Study of the Influence of Substituent R Nature in Phenylsulfones Derivatives PhSO2R on the Chemical Shifts of Phenyl Ring Protons in NMR 1H Spectra

JCCT.
2012;
Volume 6, Number 2
Authors: 

Volodymyr Mizyuk and Volodymyr Shibanov

At the explanation of the spectra peculiarities of phenylsulfones of the general formula C6H5SO2R the arguments in favour of intramolecular influence through the space of functional groups situated in fragment R on the value of phenyl protons chemical shifts iH have been adduced.

NMR 1H spectrum
phenylsulfone
basic spectral parameter
differential spectral parameters
“threshold”
intramolecular influence
space

[1] Mizyuk V. and Shibanov V.: Proceed. 12th Int. Electronic Conf. on Synthetic Organic Chemistry (ECSOC-12), 2008, А-35.
[2] Mizyuk V. and Shibanov V.: Zh. Org. i Pharmacevt. Khimii, 2011, in press.
[3] Mizyuk V. and Shibanov V.: XXII Ukrain. Conf. Organicheskoi Khimii , Ukraine, Uzhgorod 2010, 308. 
[4] Mizyuk V. and Shibanov V.:// Proceed. 13th Int. Electronic Conf. on Synthetic Organic Chemistry (ECSOC-13), 2009, G-22.
[5] Shibanov V.: Proceed. 14th Int. Electronic Conf. on Synthetic Organic Chemistry (ECSOC-14), 2010. 
[6] Mizyuk V.: Proceed. 14th Int. Electronic Conf. on Synthetic Organic Chemistry (ECSOC-14) 2010. 
[7] Mizyuk V. and Shybanov V.: Chem. & Chem. Techn., 2011, 5, 259.
[8] www.aist.go.jp
[9] Aldrich/ACD Library of FT NMR Spectra (Pro) Data Base Window