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  2. All Volumes and Issues
  3. Volume 14, Number 3, 2020
  4. Role of Supramolecular Strucutres in Mechanisms of Catalytic Oxidation and Action of Ni(Fe)ARD Dioxygenases on Model Systems

Role of Supramolecular Strucutres in Mechanisms of Catalytic Oxidation and Action of Ni(Fe)ARD Dioxygenases on Model Systems

JCCT.
2020;
Volume 14, Number 3
: pp. 304 - 311
https://doi.org/10.23939/chcht14.03.304
Authors:
  1. Ludmila Matienko
  2. Vladimir Binykov
  3. Elena Mil
  4. Gennady Zaikov
1
The Federal State Budget Institution of Science, Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Russian Federation
2
The Federal State Budget Institution of Science, Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Russian Federation
3
The Federal State Budget Institution of Science, Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Russian Federation
4
The Federal State Budget Institution of Science, Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Russian Federation

The AFM technique was used to research the possibility of the supramolecular structures formation due to H-bonds based on Ni(Fe)(acac)n-systems, that are catalysts of alkylarens oxidations and also models Ni(Fe)ARD dioxygenases: {M(acac)n+L2+L3} triple systems (M=NiII, FeIII , L2 = NMP (NMP = N-methyl-2-pirrolidone), L-histidine, L3 = PhOH, L-tyrosine), n = 2, 3). Role of H-bonding and supramolecular structures in alkylarens oxidations, catalyzed with Ni(or Fe) complexes catalysts, and also role of supramolecular structures and Tyr-fragment in mechanisms of Ni(Fe)ARD-actions is discussed.

АFМ
supramolecular structures
catalytic oxidation
O2
Ni(or Fe)(acac)n
Ni(Fe)ARD dioxygenases
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