Influence of the Silicate Modifier Nature on the Structure and Properties of Polycaproamide

Authors: 

Volodymyr Levytskyj, Victoria Kochubei and Andrij Gancho

The influence of the nature and amount of the nanosized polyvinylpyrrolidone silicate modifier obtained as a result of the combined sol-gel transition on the supramolecular structure, as well as physical, mechanical and thermo-physical properties of polycaproamide has been determined. The modifier has proved to significantly increase the degree of crystallinity of polymer, and thus tensile strength at break, surface hardness and thermal resistance of a composite.

[1] Joseph H.: Polymer Nanocomposites – Processing, Characterizations and Applications. The McGraw-Hill, New York 2006.
[2] Suresh G.: Processing and Properties of Nanocomposites. World Scientific, Singapore 2007.
[3] Guozhong C.: Nanostructures and Nanomaterials. Synthesis, Properties and Applications. Mperial college press, London 2004.
[4] Levytskyj V., Gancho А. and Suberlyak О.: Pat. Ukr. 201009105, Publ. Oct. 25, 2011.
[5] Gancho A. and Levytskyj V. Vopr. Khimii i Khim. Techn., 2010, 6, 55.
[6] Gancho A. and Levytskyj V.: Shidno-Europ. Zh. Peredovyh Techn., 2011, 52, 27.
[7] Penel-Pierron L., Seguela R., Lefebure J.-M., et. al.: Polym. Sci., 2001, 39, 1224.
[8] Usuki A., Kojima Y., Kawasumi M. and Okada A.: Mater. Res., 1993, 8, 1179.
[9] Rabiej M. and Rabiej S.: Analiza rentgenowskich krywych dyfrakcyjnych polymerów za pomoca programu komputerowego WAXSFIT. Bielsko-Biała, Warszawa 2006.