полівінілпіролідон

Physico-chemical properties of developed nickel-containing modified silicate materials as the nucleators for composites based on polyamide 6 are presented. As it was established, additive of the nucleator modified by polyvinylpyrrolidone promotes the increase of crystallinity degree of polyamide 6 and the decrease of crystallite size. It was found that changes in the structure of the material cause the increase of its tensile strength, surface hardness and Vicat softening point.

The method for obtaining composite hydrogel tubular products with the increased strength on the basis of copolymers of 2-hydroxyethylmethacrylate with polyvinylpyrrolidone has been developed. The method consists in the formation of hydrogel tubes with a subsequent precipitation from the solution into their outer surface of the reinforced layer based on polyamide, modified with polyvinylpyrrolidone.

The contact non-equilibrium low-temperature plasma technique is used to synthesize silver nanoparticles (AgNPs) employing polyvinyl pyrrolidone (PVP) as a capping agent. Influences of PVP concentration on the formation efficiency of silver nanoparticle, their average size and stability have been studied. The synthesized silver nanoparticles had a significant antibacterial activity against two strains of Gram bacteria. Silver nanoparticles (AgNPs)-alginate composite beads with different PVP concentration were synthesized as materials for water purification.

The grafted copolymerization of 2-hydroxyethyl methacrylate to polyvinylpyrrolidone in the presence of mineral fillers (hydroxyapatite, montmorillonite and wollastonite) under ultrasound has been investigated. The effect of ultrasound, nature and amount of mineral filler on the polymerization rate and composition of copolymers has been determined. Ultrasound substantially intensifies the polymerization process and actively affects the formation of the copolymer composition. Under its action, a porous structure of composites is formed, even without adding special foaming agents.

The results of investigations of the influence of main parameters (surfactant concentration and temperature) on the synthesis of silver nanoparticles (AgNPs) by the sonoelectrochemical method in polyvinylpyrrolidone (PVP) solutions by cyclic voltammetry (CVA) are presented. It is shown that the ultrasonic field (22 kHz) leads to an increase in the anodic and cathodic currents by ~30%.

The course of the grafted polymerization of 2-hydroxyethylmethacrylate on polyvinylpyrrolidone with the formation of a reticulated copolymer with simultaneously chemical reduction of nickel ions is confirmed. The influence of the reduction process on the structural parameters of the polymeric matrix – the grafting efficiency and the content of polyvinylpyrrolidone in the copolymer, the molecular weight between crosslinks is established. The influence of the presence of polymer-monomer composition components on the particles formation of nickel filler is investigated.

The patterns of obtaining in a block of porous composites based on copolymers of 2-hydroxyethylmethacrylate with polyvinylpyrrolidone in the presence of mineral fillers - glass ceramics based on silicon oxides and aluminum were investigated. We have estimated the impact of the amount and the size of inorganic filler, temperature and initiator on the polymerization rate and «maximum» monomer conversion. The results will be used to improve the technology for producing osteoplastic porous composites.

The kinetics of polymerization of 2-hydroxyethyl methacrylate with polyvinylpyrrolidone in a thin layer were studied. The dependences of the conversion for polymerization HEMA with PVP in mass and in solvent were determined. (Co)polymerization exotherms for the reaction in mass were calculated. The reaction order by initiator, monomer and polymer was determined and the mathematical dependence of the total rate of grafted copolymerization of HEMA to PVP was calculated.

The interrelation of physico-mechanical and technological characteristics of newly created nanocomposites on the basis of polypropylene (PP)/polyamide (PA-6) mixture with PVP-modified montmorillonite has been investigated. The significant impact of modified polyamide on technological, physical and mechanical properties and heat resistance of polypropylene has been determined. It has been established that the melt flow index of the resulting composites increases by more than 2 times, compared with pure PP.

Mixtures based on polypropylene (PP) and polyamide (PA) are of great importance as structural materials, the mixing of which reduces the negative characteristics of the original polymers. Non-polar PP significantly reduces water absorption of the material during mixing with polar high hydrophilic PA. As a result, the effect of moisture on the mechanical and thermal properties of the composites decreases. On the other hand, mixing PP with PA can extend the temperature range of material exploitation at negative temperatures.